Diphosphine Ligand-Enabled Nickel-Catalyzed Chelate-Assisted Inner-Selective Migratory Hydroarylation of Alkenes.
He HD, Chitrakar R, Cao ZW, Wang DM, She LQ, Zhao PG, Wu Y, Xu YQ, Cao ZY, Wang P.
He HD, et al.
Angew Chem Int Ed Engl. 2024 Jan 2;63(1):e202313336. doi: 10.1002/anie.202313336. Epub 2023 Nov 29.
Angew Chem Int Ed Engl. 2024.
PMID: 37983653
With a transient ketimine directing group, the nickel-catalyzed migratory beta-selective hydroarylation and hydroalkenylation of alkenyl ketones has been realized with aryl boronic acids using alkyl halide as the mild hydride source for the first time. The key to this succ …
With a transient ketimine directing group, the nickel-catalyzed migratory beta-selective hydroarylation and hydroalkenylation of alkenyl ket …