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Structure determination of ultra dense magnesium borohydride: a first-principles study.
J Chem Phys. 2013 Jun 7;138(21):214503. doi: 10.1063/1.4807851.
J Chem Phys. 2013.
PMID: 23758384
Magnesium borohydride (Mg(BH4)2) is one of the potential hydrogen storage materials. Recently, two experiments [Y. Filinchuk, B. Richter, T. R. Jensen, V. Dmitriev, D. Chernyshov, and H. ...
Magnesium borohydride (Mg(BH4)2) is one of the potential hydrogen storage materials. Recently, two experiments [Y. Filinchuk, …
The structure, thermal properties and phase transformations of the cubic polymorph of magnesium tetrahydroborate.
David WI, Callear SK, Jones MO, Aeberhard PC, Culligan SD, Pohl AH, Johnson SR, Ryan KR, Parker JE, Edwards PP, Nuttall CJ, Amieiro-Fonseca A.
David WI, et al.
Phys Chem Chem Phys. 2012 Sep 7;14(33):11800-7. doi: 10.1039/c2cp23439d. Epub 2012 Jul 25.
Phys Chem Chem Phys. 2012.
PMID: 22828487
The structure is found to concur with that recently determined by Filinchuk et al. (Y. Filinchuk, B. Richter, T. R. Jensen, V. Dmitriev, D. ...
The structure is found to concur with that recently determined by Filinchuk et al. (Y. Filinchuk, B. Richter, T. R. Jen …
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Thermal polymorphism and decomposition of Y(BH(4))(3).
Ravnsbaek DB, Filinchuk Y, Cerný R, Ley MB, Haase D, Jakobsen HJ, Skibsted J, Jensen TR.
Ravnsbaek DB, et al.
Inorg Chem. 2010 Apr 19;49(8):3801-9. doi: 10.1021/ic902279k.
Inorg Chem. 2010.
PMID: 20232820
The samples were prepared via a metathesis reaction between LiBH(4) and YCl(3) in different molar ratios mediated by ball milling. A new high temperature polymorph of Y(BH(4))(3), denoted beta-Y(BH(4))(3), is discovered besides the Y(BH(4))(3) polymorph previ …
The samples were prepared via a metathesis reaction between LiBH(4) and YCl(3) in different molar ratios mediated by ball milling. A new hig …
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From M(BH4)3 (M = La, Ce) Borohydride Frameworks to Controllable Synthesis of Porous Hydrides and Ion Conductors.
Ley MB, Jørgensen M, Černý R, Filinchuk Y, Jensen TR.
Ley MB, et al.
Inorg Chem. 2016 Oct 3;55(19):9748-9756. doi: 10.1021/acs.inorgchem.6b01526. Epub 2016 Sep 13.
Inorg Chem. 2016.
PMID: 27622390
The cubic c-Ce(BH(4))(3) (Fm3c) is isostructural to high-temperature polymorphs of A(BH(4))(3) (A = Y, Sm, Er, Yb) borohydrides. The larger size of the Ce(3+) ion makes the empty void in the open ReO(3)-type framework structure potentially accessible to small guest molecul …
The cubic c-Ce(BH(4))(3) (Fm3c) is isostructural to high-temperature polymorphs of A(BH(4))(3) (A = Y, Sm, Er, Yb) borohydrides. The …
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