Mononuclear Mn(III) and Mn(IV) bis-terpyridine complexes: electrochemical formation and spectroscopic characterizations.
Romain S, Baffert C, Duboc C, Leprêtre JC, Deronzier A, Collomb MN.
Romain S, et al. Among authors: duboc c.
Inorg Chem. 2009 Apr 6;48(7):3125-31. doi: 10.1021/ic8024342.
Inorg Chem. 2009.
PMID: 19326928
The one-electron oxidized form of these complexes, [Mn(III)(L)(2)](3+), has been quantitatively generated by exhaustive electrolyses at E = 1.30 V, as previously observed in the case of the oxidation of [Mn(II)(tolyl-terpy)(2)](2+) (tolyl-terpy = 4'-(4-Methylphenyl)-2,2':6',2''-t …
The one-electron oxidized form of these complexes, [Mn(III)(L)(2)](3+), has been quantitatively generated by exhaustive electrolyses at E = …