Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)-carboxylate complex

Artur Motreff; Rosenildo Correa da Costa; Hassan Allouchi; Mathieu Duttine; Corine Mathonière; Carole Duboc; Jean-Marc Vincent

doi:10.1021/ic9005218

Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)-carboxylate complex

Inorg Chem. 2009 Jul 6;48(13):5623-5. doi: 10.1021/ic9005218.

Authors

Artur Motreff¹, Rosenildo Correa da Costa, Hassan Allouchi, Mathieu Duttine, Corine Mathonière, Carole Duboc, Jean-Marc Vincent

Affiliation

¹ Institut des Sciences Moléculaires, CNRS-UMR 5255, Université Bordeaux 1, Talence, France.

PMID: 19518075
DOI: 10.1021/ic9005218

Abstract

The very fast and efficient water vapor absorption of the dimeric fluorous copper(II)-carboxylate complex [Cu(2)(C(8)F(17)CO(2))(4)(acetone)(2)] (1) leads, in the solid state, to a dramatic decrease of the exchange magnetic coupling between the copper(II) ions and to a drastic change of its powder EPR spectrum.