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1997 1
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311 results

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Page 1
Organocatalytic DYKAT of Si-Stereogenic Silanes.
Zhou H, Properzi R, Leutzsch M, Belanzoni P, Bistoni G, Tsuji N, Han JT, Zhu C, List B. Zhou H, et al. J Am Chem Soc. 2023 Mar 8;145(9):4994-5000. doi: 10.1021/jacs.3c00858. Epub 2023 Feb 24. J Am Chem Soc. 2023. PMID: 36826435 Free PMC article.
Chiral organosilanes do not exist in nature and are therefore absent from the "chiral pool". As a consequence, synthetic approaches toward enantiopure silanes, stereogenic at silicon, are rather limited. While catalytic asymmetric desymmetrization reactions of symmetric or …
Chiral organosilanes do not exist in nature and are therefore absent from the "chiral pool". As a consequence, synthetic approaches toward e …
Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silyl Ethers.
Zhou H, Han JT, Nöthling N, Lindner MM, Jenniches J, Kühn C, Tsuji N, Zhang L, List B. Zhou H, et al. J Am Chem Soc. 2022 Jun 15;144(23):10156-10161. doi: 10.1021/jacs.2c04261. Epub 2022 Jun 1. J Am Chem Soc. 2022. PMID: 35649270 Free PMC article.
The reaction proceeds via a desymmetrizing carbon-carbon bond forming silicon-hydrogen exchange reaction of symmetrical bis(methallyl)silanes with phenols using newly developed imidodiphosphorimidate (IDPi) catalysts. ...
The reaction proceeds via a desymmetrizing carbon-carbon bond forming silicon-hydrogen exchange reaction of symmetrical bis(methallyl)sil …
Antifouling Slippery Surface against Marine Biofouling.
Liu X, Gu X, Zhou Y, Pan W, Liu J, Song J. Liu X, et al. Langmuir. 2023 Sep 26;39(38):13441-13448. doi: 10.1021/acs.langmuir.3c00986. Epub 2023 Sep 1. Langmuir. 2023. PMID: 37657482
Here, based on this biomimetic idea, we develop a nontoxic antifouling slippery surface (AFSS) using silicone oil, silane coupling agent, nanosilica, nanoceramic coating, epoxy resin, and capsaicin. ...
Here, based on this biomimetic idea, we develop a nontoxic antifouling slippery surface (AFSS) using silicone oil, silane coupling ag …
Effect of silane pretreatment on the immediate bonding of universal adhesives to computer-aided design/computer-aided manufacturing lithium disilicate glass ceramics.
Yao C, Zhou L, Yang H, Wang Y, Sun H, Guo J, Huang C. Yao C, et al. Eur J Oral Sci. 2017 Apr;125(2):173-180. doi: 10.1111/eos.12340. Epub 2017 Feb 24. Eur J Oral Sci. 2017. PMID: 28233438
IPS e.max ceramic blocks etched with hydrofluoric acid were randomly assigned to one of eight groups treated with one of four universal adhesives (two silane-free adhesives and two silane-containing adhesives), each with or without silane pretreatment. ...The …
IPS e.max ceramic blocks etched with hydrofluoric acid were randomly assigned to one of eight groups treated with one of four universal adhe …
Nanoparticles having amphiphilic silane containing Chlorin e6 with strong anti-biofilm activity against periodontitis-related pathogens.
Sun X, Wang L, Lynch CD, Sun X, Li X, Qi M, Ma C, Li C, Dong B, Zhou Y, Xu HHK. Sun X, et al. J Dent. 2019 Feb;81:70-84. doi: 10.1016/j.jdent.2018.12.011. Epub 2018 Dec 26. J Dent. 2019. PMID: 30593855
MATERIALS AND METHODS: Ce6 and C6 were co-loaded into the Fe(3)O(4)-silane core-shell structure to form multifunctional nanoparticles (denoted "Fe(3)O(4)-silane@Ce6/C6 MNPs"). ...RESULTS: Fe(3)O(4)-silane@Ce6/C6 MNPs showed superparamagnetic properties, chemi …
MATERIALS AND METHODS: Ce6 and C6 were co-loaded into the Fe(3)O(4)-silane core-shell structure to form multifunctional nanoparticles …
Polymethyl(1-Butyric acidyl)silane-Assisted Dispersion and Density Gradient Ultracentrifugation Separation of Single-Walled Carbon Nanotubes.
Liu H, Zhou Q, Lian Y. Liu H, et al. Nanomaterials (Basel). 2022 Jun 17;12(12):2094. doi: 10.3390/nano12122094. Nanomaterials (Basel). 2022. PMID: 35745430 Free PMC article.
Individual single-walled carbon nanotubes (SWNTs) with distinct electronic types are crucial for the fabrication of SWNTs-based electronic and magnetic devices. Herein, the water-soluble polymethyl(1-butyric acidyl)silane (BA-PMS) was synthesized via the hydrosilylation re …
Individual single-walled carbon nanotubes (SWNTs) with distinct electronic types are crucial for the fabrication of SWNTs-based electronic a …
Assembly of Ultralong Hydroxyapatite Nanowires into Enamel-like Materials.
Wang QQ, Wu LP, Zhang S, Tao Y, Li YZ, Zhou QL, Zheng SL, Cao CY, Zhou Z, Li QL. Wang QQ, et al. J Dent Res. 2022 Sep;101(10):1181-1189. doi: 10.1177/00220345221098334. Epub 2022 Jun 16. J Dent Res. 2022. PMID: 35708455
Scanning electron microscopy and transmission electron microscopy showed that HA nanowires with aspect ratios >1,000 were assembled into enamel rod-like microstructures and evenly dispersed in the polymerized KH-570 silane matrix to form enamel-like structures. Thermogr …
Scanning electron microscopy and transmission electron microscopy showed that HA nanowires with aspect ratios >1,000 were assembled into …
N-Heterocyclic Carbene-Catalyzed Desymmetrization of Siladials To Access Silicon-Stereogenic Organosilanes.
Liu H, Zhou H, Chen X, Xu J. Liu H, et al. J Org Chem. 2022 Dec 2;87(23):16127-16137. doi: 10.1021/acs.joc.2c02184. Epub 2022 Nov 17. J Org Chem. 2022. PMID: 36395464
This desymmetrization protocol is suitable for scale-up synthesis and late-stage modifications of complex molecules, and the products can be further transformed to other enantiopure functionalized silanes....
This desymmetrization protocol is suitable for scale-up synthesis and late-stage modifications of complex molecules, and the products can be …
311 results