Lim H - Search Results

1

Dissociation of Pyridinethiolate Ligands during Hydrogen Evolution Reactions of Ni-Based Catalysts: Evidence from X-ray Absorption Spectroscopy.

Ledbetter K, Larsen CB, Lim H, Zoric MR, Koroidov S, Pemmaraju CD, Gaffney KJ, Cordones AA. Ledbetter K, et al. Among authors: lim h. Inorg Chem. 2022 Jul 4;61(26):9868-9876. doi: 10.1021/acs.inorgchem.2c00167. Epub 2022 Jun 22. Inorg Chem. 2022. PMID: 35732599 Free PMC article.

2

Metalloprotein entatic control of ligand-metal bonds quantified by ultrafast x-ray spectroscopy.

Mara MW, Hadt RG, Reinhard ME, Kroll T, Lim H, Hartsock RW, Alonso-Mori R, Chollet M, Glownia JM, Nelson S, Sokaras D, Kunnus K, Hodgson KO, Hedman B, Bergmann U, Gaffney KJ, Solomon EI. Mara MW, et al. Among authors: lim h. Science. 2017 Jun 23;356(6344):1276-1280. doi: 10.1126/science.aam6203. Science. 2017. PMID: 28642436 Free PMC article.

3

X-ray Absorption Spectroscopy as a Probe of Ligand Noninnocence in Metallocorroles: The Case of Copper Corroles.

Lim H, Thomas KE, Hedman B, Hodgson KO, Ghosh A, Solomon EI. Lim H, et al. Inorg Chem. 2019 May 20;58(10):6722-6730. doi: 10.1021/acs.inorgchem.9b00128. Epub 2019 May 2. Inorg Chem. 2019. PMID: 31046257 Free PMC article.

4

Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase.

Lim H, Baker ML, Cowley RE, Kim S, Bhadra M, Siegler MA, Kroll T, Sokaras D, Weng TC, Biswas DR, Dooley DM, Karlin KD, Hedman B, Hodgson KO, Solomon EI. Lim H, et al. Inorg Chem. 2020 Nov 16;59(22):16567-16581. doi: 10.1021/acs.inorgchem.0c02495. Epub 2020 Nov 2. Inorg Chem. 2020. PMID: 33136386 Free PMC article.

5

Short-lived metal-centered excited state initiates iron-methionine photodissociation in ferrous cytochrome c.

Reinhard ME, Mara MW, Kroll T, Lim H, Hadt RG, Alonso-Mori R, Chollet M, Glownia JM, Nelson S, Sokaras D, Kunnus K, Driel TBV, Hartsock RW, Kjaer KS, Weninger C, Biasin E, Gee LB, Hodgson KO, Hedman B, Bergmann U, Solomon EI, Gaffney KJ. Reinhard ME, et al. Among authors: lim h. Nat Commun. 2021 Feb 17;12(1):1086. doi: 10.1038/s41467-021-21423-w. Nat Commun. 2021. PMID: 33597529 Free PMC article.

6

A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity.

Bhadra M, Transue WJ, Lim H, Cowley RE, Lee JYC, Siegler MA, Josephs P, Henkel G, Lerch M, Schindler S, Neuba A, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Bhadra M, et al. Among authors: lim h. J Am Chem Soc. 2021 Mar 17;143(10):3707-3713. doi: 10.1021/jacs.1c00260. Epub 2021 Mar 8. J Am Chem Soc. 2021. PMID: 33684290 Free PMC article.

7

Kβ X-ray Emission Spectroscopy of Cu(I)-Lytic Polysaccharide Monooxygenase: Direct Observation of the Frontier Molecular Orbital for H₂O₂ Activation.

Lim H, Brueggemeyer MT, Transue WJ, Meier KK, Jones SM, Kroll T, Sokaras D, Kelemen B, Hedman B, Hodgson KO, Solomon EI. Lim H, et al. J Am Chem Soc. 2023 Jul 26;145(29):16015-16025. doi: 10.1021/jacs.3c04048. Epub 2023 Jul 13. J Am Chem Soc. 2023. PMID: 37441786 Free PMC article.

8

A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex-The Product of the Reaction of Nitrogen Monoxide (·NO_(g)) with a Ferric-Superoxide Species.

Sharma SK, Schaefer AW, Lim H, Matsumura H, Moënne-Loccoz P, Hedman B, Hodgson KO, Solomon EI, Karlin KD. Sharma SK, et al. Among authors: lim h. J Am Chem Soc. 2017 Dec 6;139(48):17421-17430. doi: 10.1021/jacs.7b08468. Epub 2017 Nov 21. J Am Chem Soc. 2017. PMID: 29091732 Free PMC article.

9

Formylglycine-generating enzyme binds substrate directly at a mononuclear Cu(I) center to initiate O₂ activation.

Appel MJ, Meier KK, Lafrance-Vanasse J, Lim H, Tsai CL, Hedman B, Hodgson KO, Tainer JA, Solomon EI, Bertozzi CR. Appel MJ, et al. Among authors: lim h. Proc Natl Acad Sci U S A. 2019 Mar 19;116(12):5370-5375. doi: 10.1073/pnas.1818274116. Epub 2019 Mar 1. Proc Natl Acad Sci U S A. 2019. PMID: 30824597 Free PMC article.

10

Tuning the Type 1 Reduction Potential of Multicopper Oxidases: Uncoupling the Effects of Electrostatics and H-Bonding to Histidine Ligands.

Singha A, Sekretareva A, Tao L, Lim H, Ha Y, Braun A, Jones SM, Hedman B, Hodgson KO, Britt RD, Kosman DJ, Solomon EI. Singha A, et al. Among authors: lim h. J Am Chem Soc. 2023 Jun 21;145(24):13284-13301. doi: 10.1021/jacs.3c03241. Epub 2023 Jun 9. J Am Chem Soc. 2023. PMID: 37294874 Free PMC article.

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