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Understanding the [NiFe] Hydrogenase Active Site Environment through Ultrafast Infrared and 2D-IR Spectroscopy of the Subsite Analogue K[CpFe(CO)(CN)2] in Polar and Protic Solvents.
Procacci B, Wrathall SLD, Farmer AL, Shaw DJ, Greetham GM, Parker AW, Rippers Y, Horch M, Lynam JM, Hunt NT. Procacci B, et al. Among authors: wrathall sld. J Phys Chem B. 2024 Feb 15;128(6):1461-1472. doi: 10.1021/acs.jpcb.3c07965. Epub 2024 Feb 1. J Phys Chem B. 2024. PMID: 38301127 Free PMC article.
Reversible Glutamate Coordination to High-Valent Nickel Protects the Active Site of a [NiFe] Hydrogenase from Oxygen.
Kulka-Peschke CJ, Schulz AC, Lorent C, Rippers Y, Wahlefeld S, Preissler J, Schulz C, Wiemann C, Bernitzky CCM, Karafoulidi-Retsou C, Wrathall SLD, Procacci B, Matsuura H, Greetham GM, Teutloff C, Lauterbach L, Higuchi Y, Ishii M, Hunt NT, Lenz O, Zebger I, Horch M. Kulka-Peschke CJ, et al. Among authors: wrathall sld. J Am Chem Soc. 2022 Sep 21;144(37):17022-17032. doi: 10.1021/jacs.2c06400. Epub 2022 Sep 9. J Am Chem Soc. 2022. PMID: 36084022