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Understanding the [NiFe] Hydrogenase Active Site Environment through Ultrafast Infrared and 2D-IR Spectroscopy of the Subsite Analogue K[CpFe(CO)(CN)2] in Polar and Protic Solvents.
J Phys Chem B. 2024 Feb 15;128(6):1461-1472. doi: 10.1021/acs.jpcb.3c07965. Epub 2024 Feb 1.
J Phys Chem B. 2024.
PMID: 38301127
Free PMC article.
Ultrafast 2D-IR spectroscopy of [NiFe] hydrogenase from E. coli reveals the role of the protein scaffold in controlling the active site environment.
Wrathall SLD, Procacci B, Horch M, Saxton E, Furlan C, Walton J, Rippers Y, Blaza JN, Greetham GM, Towrie M, Parker AW, Lynam J, Parkin A, Hunt NT.
Wrathall SLD, et al.
Phys Chem Chem Phys. 2022 Oct 19;24(40):24767-24783. doi: 10.1039/d2cp04188j.
Phys Chem Chem Phys. 2022.
PMID: 36200672
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Reversible Glutamate Coordination to High-Valent Nickel Protects the Active Site of a [NiFe] Hydrogenase from Oxygen.
Kulka-Peschke CJ, Schulz AC, Lorent C, Rippers Y, Wahlefeld S, Preissler J, Schulz C, Wiemann C, Bernitzky CCM, Karafoulidi-Retsou C, Wrathall SLD, Procacci B, Matsuura H, Greetham GM, Teutloff C, Lauterbach L, Higuchi Y, Ishii M, Hunt NT, Lenz O, Zebger I, Horch M.
Kulka-Peschke CJ, et al. Among authors: wrathall sld.
J Am Chem Soc. 2022 Sep 21;144(37):17022-17032. doi: 10.1021/jacs.2c06400. Epub 2022 Sep 9.
J Am Chem Soc. 2022.
PMID: 36084022
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Understanding the structure and dynamics of hydrogenases by ultrafast and two-dimensional infrared spectroscopy.
Horch M, Schoknecht J, Wrathall SLD, Greetham GM, Lenz O, Hunt NT.
Horch M, et al. Among authors: wrathall sld.
Chem Sci. 2019 Aug 5;10(39):8981-8989. doi: 10.1039/c9sc02851j. eCollection 2019 Oct 21.
Chem Sci. 2019.
PMID: 31762978
Free PMC article.
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