Direct observation of competitive ultrafast CO dissociation and relaxation of an MLCT excited state: picosecond time-resolved infrared spectroscopic study of [Cr(CO)(4)(2,2'-bipyridine)].
Farrell IR, Matousek P, Towrie M, Parker AW, Grills DC, George MW, Vlcek A Jr.
Farrell IR, et al. Among authors: vlcek a jr.
Inorg Chem. 2002 Aug 26;41(17):4318-23. doi: 10.1021/ic020218h.
Inorg Chem. 2002.
PMID: 12184746
Vibrationally relaxed (3)MLCT excited states are unreactive, decaying directly to the ground state on a picosecond time scale. The photoproduct is long-lived, persistent into the nanosecond time domain. ...The photochemical quantum yield of CO dissociation also decreases w …
Vibrationally relaxed (3)MLCT excited states are unreactive, decaying directly to the ground state on a picosecond time scale. The ph …