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Modular, stereocontrolled Cβ-H/Cα-C activation of alkyl carboxylic acids.
Shang M, Feu KS, Vantourout JC, Barton LM, Osswald HL, Kato N, Gagaring K, McNamara CW, Chen G, Hu L, Ni S, Fernández-Canelas P, Chen M, Merchant RR, Qin T, Schreiber SL, Melillo B, Yu JQ, Baran PS. Shang M, et al. Among authors: vantourout jc. Proc Natl Acad Sci U S A. 2019 Apr 30;116(18):8721-8727. doi: 10.1073/pnas.1903048116. Epub 2019 Apr 17. Proc Natl Acad Sci U S A. 2019. PMID: 30996125 Free PMC article.
Electrochemically Enabled, Nickel-Catalyzed Amination.
Li C, Kawamata Y, Nakamura H, Vantourout JC, Liu Z, Hou Q, Bao D, Starr JT, Chen J, Yan M, Baran PS. Li C, et al. Among authors: vantourout jc. Angew Chem Int Ed Engl. 2017 Oct 9;56(42):13088-13093. doi: 10.1002/anie.201707906. Epub 2017 Sep 14. Angew Chem Int Ed Engl. 2017. PMID: 28834098 Free PMC article.
Unlocking P(V): Reagents for chiral phosphorothioate synthesis.
Knouse KW, deGruyter JN, Schmidt MA, Zheng B, Vantourout JC, Kingston C, Mercer SE, Mcdonald IM, Olson RE, Zhu Y, Hang C, Zhu J, Yuan C, Wang Q, Park P, Eastgate MD, Baran PS. Knouse KW, et al. Among authors: vantourout jc. Science. 2018 Sep 21;361(6408):1234-1238. doi: 10.1126/science.aau3369. Epub 2018 Aug 2. Science. 2018. PMID: 30072577 Free PMC article.
Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications.
Kawamata Y, Vantourout JC, Hickey DP, Bai P, Chen L, Hou Q, Qiao W, Barman K, Edwards MA, Garrido-Castro AF, deGruyter JN, Nakamura H, Knouse K, Qin C, Clay KJ, Bao D, Li C, Starr JT, Garcia-Irizarry C, Sach N, White HS, Neurock M, Minteer SD, Baran PS. Kawamata Y, et al. Among authors: vantourout jc. J Am Chem Soc. 2019 Apr 17;141(15):6392-6402. doi: 10.1021/jacs.9b01886. Epub 2019 Apr 2. J Am Chem Soc. 2019. PMID: 30905151 Free PMC article.
A Radical Approach to Anionic Chemistry: Synthesis of Ketones, Alcohols, and Amines.
Ni S, Padial NM, Kingston C, Vantourout JC, Schmitt DC, Edwards JT, Kruszyk MM, Merchant RR, Mykhailiuk PK, Sanchez BB, Yang S, Perry MA, Gallego GM, Mousseau JJ, Collins MR, Cherney RJ, Lebed PS, Chen JS, Qin T, Baran PS. Ni S, et al. Among authors: vantourout jc. J Am Chem Soc. 2019 Apr 24;141(16):6726-6739. doi: 10.1021/jacs.9b02238. Epub 2019 Apr 16. J Am Chem Soc. 2019. PMID: 30943023 Free PMC article.
Expanding Reactivity in DNA-Encoded Library Synthesis via Reversible Binding of DNA to an Inert Quaternary Ammonium Support.
Flood DT, Asai S, Zhang X, Wang J, Yoon L, Adams ZC, Dillingham BC, Sanchez BB, Vantourout JC, Flanagan ME, Piotrowski DW, Richardson P, Green SA, Shenvi RA, Chen JS, Baran PS, Dawson PE. Flood DT, et al. Among authors: vantourout jc. J Am Chem Soc. 2019 Jun 26;141(25):9998-10006. doi: 10.1021/jacs.9b03774. Epub 2019 Jun 12. J Am Chem Soc. 2019. PMID: 31136164 Free PMC article.
A Survival Guide for the "Electro-curious".
Kingston C, Palkowitz MD, Takahira Y, Vantourout JC, Peters BK, Kawamata Y, Baran PS. Kingston C, et al. Among authors: vantourout jc. Acc Chem Res. 2020 Jan 21;53(1):72-83. doi: 10.1021/acs.accounts.9b00539. Epub 2019 Dec 11. Acc Chem Res. 2020. PMID: 31823612 Free PMC article. Review.
Electrochemical Decarboxylative N-Alkylation of Heterocycles.
Sheng T, Zhang HJ, Shang M, He C, Vantourout JC, Baran PS. Sheng T, et al. Among authors: vantourout jc. Org Lett. 2020 Oct 2;22(19):7594-7598. doi: 10.1021/acs.orglett.0c02799. Epub 2020 Sep 17. Org Lett. 2020. PMID: 32941044 Free PMC article.
Serine-Selective Bioconjugation.
Vantourout JC, Adusumalli SR, Knouse KW, Flood DT, Ramirez A, Padial NM, Istrate A, Maziarz K, deGruyter JN, Merchant RR, Qiao JX, Schmidt MA, Deery MJ, Eastgate MD, Dawson PE, Bernardes GJL, Baran PS. Vantourout JC, et al. J Am Chem Soc. 2020 Oct 14;142(41):17236-17242. doi: 10.1021/jacs.0c05595. Epub 2020 Oct 5. J Am Chem Soc. 2020. PMID: 32965106 Free PMC article.
36 results