Kinetic effects of hydrogen bonds on proton-coupled electron transfer from phenols.
Sjödin M, Irebo T, Utas JE, Lind J, Merényi G, Akermark B, Hammarström L.
Sjödin M, et al.
J Am Chem Soc. 2006 Oct 11;128(40):13076-83. doi: 10.1021/ja063264f.
J Am Chem Soc. 2006.
PMID: 17017787
Without internal hydrogen bonds the concerted mechanism gave a characteristic pH-dependent rate for the phenol form that followed a Marcus free energy dependence, first reported for an intramolecular PCET in Sjodin, M. et al. J. Am. Chem. Soc. 2000, 122, 3932-3962 a …
Without internal hydrogen bonds the concerted mechanism gave a characteristic pH-dependent rate for the phenol form that followed a Marcus f …