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Reversible Glutamate Coordination to High-Valent Nickel Protects the Active Site of a [NiFe] Hydrogenase from Oxygen.
Kulka-Peschke CJ, Schulz AC, Lorent C, Rippers Y, Wahlefeld S, Preissler J, Schulz C, Wiemann C, Bernitzky CCM, Karafoulidi-Retsou C, Wrathall SLD, Procacci B, Matsuura H, Greetham GM, Teutloff C, Lauterbach L, Higuchi Y, Ishii M, Hunt NT, Lenz O, Zebger I, Horch M. Kulka-Peschke CJ, et al. Among authors: rippers y. J Am Chem Soc. 2022 Sep 21;144(37):17022-17032. doi: 10.1021/jacs.2c06400. Epub 2022 Sep 9. J Am Chem Soc. 2022. PMID: 36084022
Resonance Raman spectroscopy as a tool to monitor the active site of hydrogenases.
Siebert E, Horch M, Rippers Y, Fritsch J, Frielingsdorf S, Lenz O, Velazquez Escobar F, Siebert F, Paasche L, Kuhlmann U, Lendzian F, Mroginski MA, Zebger I, Hildebrandt P. Siebert E, et al. Among authors: rippers y. Angew Chem Int Ed Engl. 2013 May 3;52(19):5162-5. doi: 10.1002/anie.201209732. Epub 2013 Apr 22. Angew Chem Int Ed Engl. 2013. PMID: 23610008 No abstract available.
Reversible [4Fe-3S] cluster morphing in an O(2)-tolerant [NiFe] hydrogenase.
Frielingsdorf S, Fritsch J, Schmidt A, Hammer M, Löwenstein J, Siebert E, Pelmenschikov V, Jaenicke T, Kalms J, Rippers Y, Lendzian F, Zebger I, Teutloff C, Kaupp M, Bittl R, Hildebrandt P, Friedrich B, Lenz O, Scheerer P. Frielingsdorf S, et al. Among authors: rippers y. Nat Chem Biol. 2014 May;10(5):378-85. doi: 10.1038/nchembio.1500. Epub 2014 Apr 6. Nat Chem Biol. 2014. PMID: 24705592
Resonance Raman Spectroscopic Analysis of the [NiFe] Active Site and the Proximal [4Fe-3S] Cluster of an O2-Tolerant Membrane-Bound Hydrogenase in the Crystalline State.
Siebert E, Rippers Y, Frielingsdorf S, Fritsch J, Schmidt A, Kalms J, Katz S, Lenz O, Scheerer P, Paasche L, Pelmenschikov V, Kuhlmann U, Mroginski MA, Zebger I, Hildebrandt P. Siebert E, et al. Among authors: rippers y. J Phys Chem B. 2015 Oct 29;119(43):13785-96. doi: 10.1021/acs.jpcb.5b04119. Epub 2015 Aug 7. J Phys Chem B. 2015. PMID: 26201814
Ultrafast 2D-IR spectroscopy of [NiFe] hydrogenase from E. coli reveals the role of the protein scaffold in controlling the active site environment.
Wrathall SLD, Procacci B, Horch M, Saxton E, Furlan C, Walton J, Rippers Y, Blaza JN, Greetham GM, Towrie M, Parker AW, Lynam J, Parkin A, Hunt NT. Wrathall SLD, et al. Among authors: rippers y. Phys Chem Chem Phys. 2022 Oct 19;24(40):24767-24783. doi: 10.1039/d2cp04188j. Phys Chem Chem Phys. 2022. PMID: 36200672
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