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Bioinspired Binickel Catalyst for Carbon Dioxide Reduction: The Importance of Metal-ligand Cooperation.
Xiao Y, Xie F, Zhang HT, Zhang MT. Xiao Y, et al. JACS Au. 2024 Mar 11;4(3):1207-1218. doi: 10.1021/jacsau.4c00047. eCollection 2024 Mar 25. JACS Au. 2024. PMID: 38559717 Free PMC article.
Enlightened by bimetallic synergy, we herein report a dinickel complex, Ni(II)Ni(II)(bphpp)(AcO)(2) (where NiNi(bphpp) is derived from H(2)bphpp = 2,9-bis(5-tert-butyl-2-hydroxy-3-pyridylphenyl)-1,10-phenanthroline) for electrocatalytic reduction of CO(2) to CO, which exhi …
Enlightened by bimetallic synergy, we herein report a dinickel complex, Ni(II)Ni(II)(bphpp)(AcO)(2) (where NiNi(bphpp) is derived fro …
Unusual NiNi interaction in Ni(ii) complexes as potential inhibitors for the development of new anti-SARS-CoV-2 Omicron drugs.
Singh S, Choudhary M. Singh S, et al. RSC Med Chem. 2024 Feb 20;15(3):895-915. doi: 10.1039/d3md00601h. eCollection 2024 Mar 20. RSC Med Chem. 2024. PMID: 38516589
Both square planar Ni(ii) complexes were often stacked with relatively short NiNi distances. The non-bonded Ni-Ni distance (NiNi separation) seems to be 3.356 A and 3.214 A from the nickel atoms of [Ni(L)](2)(1) and [Ni(L)](n)(2), respectively. These distances are s …
Both square planar Ni(ii) complexes were often stacked with relatively short NiNi distances. The non-bonded Ni-Ni distance (NiNi …
659 results