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Oxidation of glycosphingolipids under basic conditions: synthesis of glycosyl "serine acids" as opposed to "ceramide acids". Precursors for neoglycoconjugates with increased ligand binding affinity.
Mylvaganam M, Meng L, Lingwood CA. Mylvaganam M, et al. Biochemistry. 1999 Aug 17;38(33):10885-97. doi: 10.1021/bi990669m. Biochemistry. 1999. PMID: 10451385
Oxidation of peracetylated GSL precursors with stoichiometric proportions of KMnO4 and an excess of NaIO4, in a neutral aqueous tert-butanol solvent system, gave nearly quantitative yields of the glycosyl ceramide acid, 2-hydroxy-3-(N-acyl)-4-(O-glycosyl)oxybutyric acid [Mylva …
Oxidation of peracetylated GSL precursors with stoichiometric proportions of KMnO4 and an excess of NaIO4, in a neutral aqueous tert-butanol …
New aspects of the regulation of glycosphingolipid receptor function.
Lingwood CA, Manis A, Mahfoud R, Khan F, Binnington B, Mylvaganam M. Lingwood CA, et al. Among authors: mylvaganam m. Chem Phys Lipids. 2010 Jan;163(1):27-35. doi: 10.1016/j.chemphyslip.2009.09.001. Chem Phys Lipids. 2010. PMID: 19781539 Review.
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