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Catalytic cycle for the asymmetric hydrogenation of prochiral ketones to chiral alcohols: direct hydride and proton transfer from chiral catalysts trans-Ru(H)(2)(diphosphine)(diamine) to ketones and direct addition of dihydrogen to the resulting hydridoamido complexes.
Abdur-Rashid K, Faatz M, Lough AJ, Morris RH. Abdur-Rashid K, et al. Among authors: morris rh. J Am Chem Soc. 2001 Aug 1;123(30):7473-4. doi: 10.1021/ja015902u. J Am Chem Soc. 2001. PMID: 11472199 No abstract available.
163 results