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Th@C1(11)-C86: an actinide encapsulated in an unexpected C86 fullerene cage.
Wang Y, Morales-Martínez R, Cai W, Zhuang J, Yang W, Echegoyen L, Poblet JM, Rodríguez-Fortea A, Chen N. Wang Y, et al. Among authors: morales martinez r. Chem Commun (Camb). 2019 Aug 14;55(63):9271-9274. doi: 10.1039/c9cc04613e. Epub 2019 Jul 12. Chem Commun (Camb). 2019. PMID: 31298675
Single crystal structures and theoretical calculations of uranium endohedral metallofullerenes (U@C2n , 2n = 74, 82) show cage isomer dependent oxidation states for U.
Cai W, Morales-Martínez R, Zhang X, Najera D, Romero EL, Metta-Magaña A, Rodríguez-Fortea A, Fortier S, Chen N, Poblet JM, Echegoyen L. Cai W, et al. Among authors: morales martinez r. Chem Sci. 2017 Aug 1;8(8):5282-5290. doi: 10.1039/c7sc01711a. Epub 2017 May 22. Chem Sci. 2017. PMID: 28970908 Free PMC article.
Synthesis and Characterization of Non-Isolated-Pentagon-Rule Actinide Endohedral Metallofullerenes U@ C1(17418)-C76, U@ C1(28324)-C80, and Th@ C1(28324)-C80: Low-Symmetry Cage Selection Directed by a Tetravalent Ion.
Cai W, Abella L, Zhuang J, Zhang X, Feng L, Wang Y, Morales-Martínez R, Esper R, Boero M, Metta-Magaña A, Rodríguez-Fortea A, Poblet JM, Echegoyen L, Chen N. Cai W, et al. Among authors: morales martinez r. J Am Chem Soc. 2018 Dec 26;140(51):18039-18050. doi: 10.1021/jacs.8b10435. Epub 2018 Dec 4. J Am Chem Soc. 2018. PMID: 30453733
Purification of Uranium-based Endohedral Metallofullerenes (EMFs) by Selective Supramolecular Encapsulation and Release.
Fuertes-Espinosa C, Gómez-Torres A, Morales-Martínez R, Rodríguez-Fortea A, García-Simón C, Gándara F, Imaz I, Juanhuix J, Maspoch D, Poblet JM, Echegoyen L, Ribas X. Fuertes-Espinosa C, et al. Among authors: morales martinez r. Angew Chem Int Ed Engl. 2018 Aug 27;57(35):11294-11299. doi: 10.1002/anie.201806140. Epub 2018 Jul 26. Angew Chem Int Ed Engl. 2018. PMID: 29917307