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Ferricyanide photo-aquation pathway revealed by combined femtosecond Kβ main line and valence-to-core x-ray emission spectroscopy.
Reinhard M, Gallo A, Guo M, Garcia-Esparza AT, Biasin E, Qureshi M, Britz A, Ledbetter K, Kunnus K, Weninger C, van Driel T, Robinson J, Glownia JM, Gaffney KJ, Kroll T, Weng TC, Alonso-Mori R, Sokaras D. Reinhard M, et al. Among authors: kunnus k. Nat Commun. 2023 May 5;14(1):2443. doi: 10.1038/s41467-023-37922-x. Nat Commun. 2023. PMID: 37147295 Free PMC article.
Orbital-specific mapping of the ligand exchange dynamics of Fe(CO)5 in solution.
Wernet P, Kunnus K, Josefsson I, Rajkovic I, Quevedo W, Beye M, Schreck S, Grübel S, Scholz M, Nordlund D, Zhang W, Hartsock RW, Schlotter WF, Turner JJ, Kennedy B, Hennies F, de Groot FM, Gaffney KJ, Techert S, Odelius M, Föhlisch A. Wernet P, et al. Among authors: kunnus k. Nature. 2015 Apr 2;520(7545):78-81. doi: 10.1038/nature14296. Nature. 2015. PMID: 25832405
Identification of the dominant photochemical pathways and mechanistic insights to the ultrafast ligand exchange of Fe(CO)5 to Fe(CO)4EtOH.
Kunnus K, Josefsson I, Rajkovic I, Schreck S, Quevedo W, Beye M, Weniger C, Grübel S, Scholz M, Nordlund D, Zhang W, Hartsock RW, Gaffney KJ, Schlotter WF, Turner JJ, Kennedy B, Hennies F, de Groot FM, Techert S, Odelius M, Wernet P, Föhlisch A. Kunnus K, et al. Struct Dyn. 2016 Feb 9;3(4):043204. doi: 10.1063/1.4941602. eCollection 2016 Jul. Struct Dyn. 2016. PMID: 26958587 Free PMC article.
Solvent control of charge transfer excited state relaxation pathways in [Fe(2,2'-bipyridine)(CN)4]2.
Kjær KS , Kunnus K , Harlang TCB , Van Driel TB , Ledbetter K , Hartsock RW , Reinhard ME , Koroidov S , Li L , Laursen MG , Biasin E , Hansen FB , Vester P , Christensen M , Haldrup K , Nielsen MM , Chabera P , Liu Y , Tatsuno H , Timm C , Uhlig J , Sundstöm V , Németh Z , Szemes DS , Bajnóczi É , Vankó G , Alonso-Mori R , Glownia JM , Nelson S , Sikorski M , Sokaras D , Lemke HT , Canton SE , Wärnmark K , Persson P , Cordones AA , Gaffney KJ . Kjær KS , et al. Among authors: kunnus k. Phys Chem Chem Phys. 2018 Feb 7;20(6):4238-4249. doi: 10.1039/c7cp07838b. Phys Chem Chem Phys. 2018. PMID: 29364300
Disentangling Transient Charge Density and Metal-Ligand Covalency in Photoexcited Ferricyanide with Femtosecond Resonant Inelastic Soft X-ray Scattering.
Jay RM, Norell J, Eckert S, Hantschmann M, Beye M, Kennedy B, Quevedo W, Schlotter WF, Dakovski GL, Minitti MP, Hoffmann MC, Mitra A, Moeller SP, Nordlund D, Zhang W, Liang HW, Kunnus K, Kubiček K, Techert SA, Lundberg M, Wernet P, Gaffney K, Odelius M, Föhlisch A. Jay RM, et al. Among authors: kunnus k. J Phys Chem Lett. 2018 Jun 21;9(12):3538-3543. doi: 10.1021/acs.jpclett.8b01429. Epub 2018 Jun 14. J Phys Chem Lett. 2018. PMID: 29888918 Free article.
Probing the Electron Accepting Orbitals of Ni-Centered Hydrogen Evolution Catalysts with Noninnocent Ligands by Ni L-Edge and S K-Edge X-ray Absorption.
Koroidov S, Hong K, Kjaer KS, Li L, Kunnus K, Reinhard M, Hartsock RW, Amit D, Eisenberg R, Pemmaraju CD, Gaffney KJ, Cordones AA. Koroidov S, et al. Among authors: kunnus k. Inorg Chem. 2018 Nov 5;57(21):13167-13175. doi: 10.1021/acs.inorgchem.8b01497. Epub 2018 Oct 11. Inorg Chem. 2018. PMID: 30351073
33 results