Photochemical behavior of (bisphosphane)(η(2)-tolane)Pt(0) complexes. Part B: An insight from DFT calculations.
Escudero D, Weisheit T, Weigand W, González L.
Escudero D, et al. Among authors: gonzalez l.
Dalton Trans. 2010 Oct 28;39(40):9505-13. doi: 10.1039/b925928g. Epub 2010 Sep 10.
Dalton Trans. 2010.
PMID: 20830427
The observed photochemical C(aryl)-C(ethynyl) bond cleavage is, oppositely to C-Br bond activation, reversible under thermal conditions regaining the appropriate Pt(0) complexes by reductive elimination (see T. Weisheit, D. Escudero, H. Petzold, H. Gorls, L. Gonzalez …
The observed photochemical C(aryl)-C(ethynyl) bond cleavage is, oppositely to C-Br bond activation, reversible under thermal conditions rega …