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Enzymatic spiroketal formation via oxidative rearrangement of pentangular polyketides.
Nat Commun. 2021 Mar 4;12(1):1431. doi: 10.1038/s41467-021-21432-9.
Nat Commun. 2021.
PMID: 33664266
Free PMC article.
An acetyltransferase controls the metabolic flux in rubromycin polyketide biosynthesis by direct modulation of redox tailoring enzymes.
Toplak M, Nagel A, Frensch B, Lechtenberg T, Teufel R.
Toplak M, et al. Among authors: frensch b.
Chem Sci. 2022 May 17;13(24):7157-7164. doi: 10.1039/d2sc01952c. eCollection 2022 Jun 22.
Chem Sci. 2022.
PMID: 35799824
Free PMC article.
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Oxidative Carbon Backbone Rearrangement in Rishirilide Biosynthesis.
Tsypik O, Makitrynskyy R, Frensch B, Zechel DL, Paululat T, Teufel R, Bechthold A.
Tsypik O, et al. Among authors: frensch b.
J Am Chem Soc. 2020 Apr 1;142(13):5913-5917. doi: 10.1021/jacs.9b12736. Epub 2020 Mar 19.
J Am Chem Soc. 2020.
PMID: 32182053
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