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1972 5
1973 11
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Page 1
Showing results for formed pi
Search for Former Pi instead (1 results)
Ethyl 2-[4-(4-meth-oxy-benz-yl)-3-methyl-6-oxopyridazin-1-yl]acetate.
Zaoui Y, Assila H, Mague JT, Alsubari A, Taoufik J, Ramli Y, Ansar M. Zaoui Y, et al. IUCrdata. 2022 Jun 7;7(Pt 6):x220582. doi: 10.1107/S241431462200582X. eCollection 2022 Jun. IUCrdata. 2022. PMID: 36339895 Free PMC article.
In the title mol-ecule, C(17)H(20)N(2)O(4), the inner part of the ester substituent is nearly perpendicular to the di-hydro-pyridazine ring, forming a dihedral angle of 83.21 (7). In the crystal, inversion dimers are formed by pairwise C-HO inter-actions with the di …
In the title mol-ecule, C(17)H(20)N(2)O(4), the inner part of the ester substituent is nearly perpendicular to the di-hydro-pyridazine ring, …
Is pi halogen bonding or lone pair...pi interaction formed between borazine and some halogenated compounds?
Zhuo H, Li Q, Li W, Cheng J. Zhuo H, et al. Phys Chem Chem Phys. 2014 Jan 7;16(1):159-65. doi: 10.1039/c3cp54006e. Phys Chem Chem Phys. 2014. PMID: 24232521
It was known that benzene is favorable to form halogen bonds with halogenated molecules. However, borazine more easily forms lone pair-pi interactions with halogenated molecules, but for stronger halogen donors it can also form halogen bonds. The halogen bonds fo
It was known that benzene is favorable to form halogen bonds with halogenated molecules. However, borazine more easily forms lone pai …
Palladium(0) pi-Lewis Base Catalysis: Concept and Development.
Chen ZC, Ouyang Q, Du W, Chen YC. Chen ZC, et al. J Am Chem Soc. 2024 Mar 13;146(10):6422-6437. doi: 10.1021/jacs.3c14674. Epub 2024 Mar 1. J Am Chem Soc. 2024. PMID: 38426858 Review.
The development of a new catalytic strategy plays a vital role in modern organic chemistry since it permits bond formation in an unprecedented and more efficient manner. Although the application of preformed metal complexes as pi-base-activated reagents have enabled divers …
The development of a new catalytic strategy plays a vital role in modern organic chemistry since it permits bond formation in an unprecedent …
3-Ethyl-2-methyl-5-methyl-ene-6,7-di-hydroindol-4(5H)-one.
Sonar VN, Parkin S, Crooks PA. Sonar VN, et al. Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):o158. doi: 10.1107/S1600536807063076. Acta Crystallogr Sect E Struct Rep Online. 2007. PMID: 21200723 Free PMC article.
The title compound, C(12)H(15)NO, a degradation product of molindone hydro-chloride, was prepared by the reaction of molindone with methyl iodide and subsequent reaction of the resulting quaternary ammonium salt with 2N aqueous sodium hydroxide. The newly formed double bon …
The title compound, C(12)H(15)NO, a degradation product of molindone hydro-chloride, was prepared by the reaction of molindone with methyl i …
Nanofibers formed through pi...pi stacking of the complexes of glucosyl-C2-salicyl-imine and phenylalanine: characterization by microscopy, modeling by molecular mechanics, and interaction by alpha-helical and beta-sheet proteins.
Acharya A, Ramanujam B, Mitra A, Rao CP. Acharya A, et al. ACS Nano. 2010 Jul 27;4(7):4061-73. doi: 10.1021/nn1006286. ACS Nano. 2010. PMID: 20521836
This paper deals with the self-assembly of the 1:1 complex of two different amphiphiles, namely, a glucosyl-salicyl-imino conjugate (L) and phenylalanine (Phe), forming nanofibers over a period of time through pi...pi interactions. ...Similar spectral and mic …
This paper deals with the self-assembly of the 1:1 complex of two different amphiphiles, namely, a glucosyl-salicyl-imino conjugate (L) and …
The ER/PM microdomain, PI(4,5)P2 and the regulation of STIM1-Orai1 channel function.
Cao X, Choi S, Maléth JJ, Park S, Ahuja M, Muallem S. Cao X, et al. Cell Calcium. 2015 Oct;58(4):342-8. doi: 10.1016/j.ceca.2015.03.003. Epub 2015 Mar 18. Cell Calcium. 2015. PMID: 25843208 Free PMC article. Review.
All forms of cell signaling occur in discreet cellular microdomains in which the ER is the main participant and include microdomains formed by the ER with lysosomes, endosomes, the nucleus, mitochondria and the plasma membrane. ...This review discusses recent advanc …
All forms of cell signaling occur in discreet cellular microdomains in which the ER is the main participant and include microdomains …
Aromatic Polyphenol pi-pi Interactions with Superoxide Radicals Contribute to Radical Scavenging and Can Make Polyphenols Mimic Superoxide Dismutase Activity.
Caruso F, Incerpi S, Pedersen J, Belli S, Kaur S, Rossi M. Caruso F, et al. Curr Issues Mol Biol. 2022 Oct 26;44(11):5209-5220. doi: 10.3390/cimb44110354. Curr Issues Mol Biol. 2022. PMID: 36354666 Free PMC article. Review.
Mechanistically, it is very difficult to establish if this pi-pi interaction proceeds before or after the most common mode of scavenging superoxide, e.g., abstraction of an aromatic polyphenol H(hydroxyl), which then is used to form H(2)O(2) (the other molecule prod …
Mechanistically, it is very difficult to establish if this pi-pi interaction proceeds before or after the most common mode of …
Chromatofocusing.
Li CM, William Hutchens T. Li CM, et al. Methods Mol Biol. 1992;11:237-48. doi: 10.1385/0-89603-213-2:237. Methods Mol Biol. 1992. PMID: 21431670
The pH gradient is formed internally during isocratic elution with a single focusing buffer; no external gradient forming device is required. The pH gradient is formed as the eluting buffer (i.e., focusing buffer) titrates the buffering groups on the ion exch …
The pH gradient is formed internally during isocratic elution with a single focusing buffer; no external gradient forming devi …
Thermal Transport in Poly(p-phenylene): Anomalous Dimensionality Dependence and Role of pi-pi Stacking.
Yang C, Raza S, Li X, Liu J. Yang C, et al. J Phys Chem B. 2023 Aug 3;127(30):6804-6813. doi: 10.1021/acs.jpcb.3c02947. Epub 2023 Jul 21. J Phys Chem B. 2023. PMID: 37478475
Intuitively, for chains with an aromatic backbone, the even stronger pi-pi stacking, once formed between chains, should enhance thermal transport across chains and suppress the thermal conductivity along the chains. ...We analyzed the probability distribution …
Intuitively, for chains with an aromatic backbone, the even stronger pi-pi stacking, once formed between chains, should …
4-[(E)-2-Ferrocenylethen-yl]-1,8-naphthalic anhydride.
Munro NH, Hanton LR, McAdam CJ, McMorran DA. Munro NH, et al. Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 29;64(Pt 4):m572. doi: 10.1107/S1600536808007393. Acta Crystallogr Sect E Struct Rep Online. 2008. PMID: 21202023 Free PMC article.
In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6) with respect to the mean plane through the naphthalene ring system. In the crystal structure, centrosymmetric dimers are formed throug …
In the structure of the title compound, [Fe(C(5)H(5))(C(19)H(11)O(3))], the plane of the substituted ferrocene ring is tilted by 14.17 (6) w …
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