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Reactive high-spin iron(IV)-oxo sites through dioxygen activation in a metal-organic framework.
Hou K, Börgel J, Jiang HZH, SantaLucia DJ, Kwon H, Zhuang H, Chakarawet K, Rohde RC, Taylor JW, Dun C, Paley MV, Turkiewicz AB, Park JG, Mao H, Zhu Z, Alp EE, Zhao J, Hu MY, Lavina B, Peredkov S, Lv X, Oktawiec J, Meihaus KR, Pantazis DA, Vandone M, Colombo V, Bill E, Urban JJ, Britt RD, Grandjean F, Long GJ, DeBeer S, Neese F, Reimer JA, Long JR. Hou K, et al. Among authors: debeer s. Science. 2023 Nov 3;382(6670):547-553. doi: 10.1126/science.add7417. Epub 2023 Nov 2. Science. 2023. PMID: 37917685 Free article.
Experimental and computational X-ray emission spectroscopy as a direct probe of protonation states in oxo-bridged Mn(IV) dimers relevant to redox-active metalloproteins.
Lassalle-Kaiser B, Boron TT 3rd, Krewald V, Kern J, Beckwith MA, Delgado-Jaime MU, Schroeder H, Alonso-Mori R, Nordlund D, Weng TC, Sokaras D, Neese F, Bergmann U, Yachandra VK, DeBeer S, Pecoraro VL, Yano J. Lassalle-Kaiser B, et al. Among authors: debeer s. Inorg Chem. 2013 Nov 18;52(22):12915-22. doi: 10.1021/ic400821g. Epub 2013 Oct 25. Inorg Chem. 2013. PMID: 24161081 Free PMC article.
212 results