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Switchable chemoselective aryne reactions between nucleophiles and pericyclic reaction partners using either 3-methoxybenzyne or 3-silylbenzyne.
Nat Commun. 2024 Apr 30;15(1):3665. doi: 10.1038/s41467-024-47952-8.
Nat Commun. 2024.
PMID: 38693115
Free PMC article.
Aryne 1,4-Disubstitution and Remote Diastereoselective 1,2,4-Trisubstitution via a Nucleophilic Annulation-[5,5]-Sigmatropic Rearrangement Process.
Chen Z, Tan M, Shan C, Yuan X, Chen L, Shi J, Lan Y, Li Y.
Chen Z, et al.
Angew Chem Int Ed Engl. 2022 Nov 21;61(47):e202212160. doi: 10.1002/anie.202212160. Epub 2022 Oct 25.
Angew Chem Int Ed Engl. 2022.
PMID: 36180383
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