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Rhodium-Catalyzed Asymmetric Hydrogenation and Transfer Hydrogenation of 1,3-Dipolar Nitrones.
Angew Chem Int Ed Engl. 2024 Apr 2;63(14):e202319662. doi: 10.1002/anie.202319662. Epub 2024 Feb 29.
Angew Chem Int Ed Engl. 2024.
PMID: 38366812
Copper-Catalyzed Chemo- and Enantioselective Radical 1,2-Carbophosphonylation of Styrenes.
Zhou H, Fan LW, Ren YQ, Wang LL, Yang CJ, Gu QS, Li ZL, Liu XY.
Zhou H, et al.
Angew Chem Int Ed Engl. 2023 Mar 20;62(13):e202218523. doi: 10.1002/anie.202218523. Epub 2023 Feb 16.
Angew Chem Int Ed Engl. 2023.
PMID: 36722939
We herein disclose a radical 1,2-carbophosphonylation of styrenes in a highly chemo- and enantioselective manner. The key to the success lies in not only the implementation of dialkyl phosphites with a strong bond dissociation energy to promote the desired chemoselectivity …
We herein disclose a radical 1,2-carbophosphonylation of styrenes in a highly chemo- and enantioselective manner. The key to the succ …
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Copper-Catalyzed Enantioconvergent Radical C(sp3 )-N Cross-Coupling: Access to α,α-Disubstituted Amino Acids.
Zhang YF, Wang JH, Yang NY, Chen Z, Wang LL, Gu QS, Li ZL, Liu XY.
Zhang YF, et al.
Angew Chem Int Ed Engl. 2023 Jul 3;62(27):e202302983. doi: 10.1002/anie.202302983. Epub 2023 May 22.
Angew Chem Int Ed Engl. 2023.
PMID: 37154671
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Copper-Catalyzed Enantioselective C(sp3 )-SCF3 Coupling of Carbon-Centered Benzyl Radicals with (Me4 N)SCF3.
Zhang W, Tian Y, Liu XD, Luan C, Liu JR, Gu QS, Li ZL, Liu XY.
Zhang W, et al.
Angew Chem Int Ed Engl. 2024 Mar 11;63(11):e202319850. doi: 10.1002/anie.202319850. Epub 2024 Feb 8.
Angew Chem Int Ed Engl. 2024.
PMID: 38273811
We herein disclose a copper-catalyzed enantioselective radical C(sp(3) )-SCF(3) coupling of a range of secondary/tertiary benzyl radicals with the easily available (Me(4) N)SCF(3) reagent. The key to the success lies in the utilization of chiral phosphino-oxazoline-derived …
We herein disclose a copper-catalyzed enantioselective radical C(sp(3) )-SCF(3) coupling of a range of secondary/tertiary benzyl radicals wi …
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