A fluorescent thermometer operating in aggregation-induced emission mechanism: probing thermal transitions of PNIPAM in water

Chem Commun (Camb). 2009 Sep 7:(33):4974-6. doi: 10.1039/b907382e. Epub 2009 Jul 10.

Abstract

Poly(N-isopropylacrylamide) was labelled using a fluorogen with an aggregation-induced emission feature by direct polymerization; the label served as a fluorogenic probe that reveals fine details in the thermal transitions in the aqueous solution of the polymer; the working mode was readily tuned between non-monotonic and monotonic by changing the labelling degree of the polymer.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acrylamides / chemistry*
  • Acrylic Resins
  • Fluorescent Dyes / chemistry*
  • Polymers / chemistry*
  • Spectrometry, Fluorescence
  • Temperature
  • Thermometers*
  • Water / chemistry*

Substances

  • Acrylamides
  • Acrylic Resins
  • Fluorescent Dyes
  • Polymers
  • Water
  • poly-N-isopropylacrylamide