Cyanide as a bridge can be used to construct homo- and heterometallic complexes with intriguing structures and interesting magnetic properties. These ligands can generate diverse structures, including clusters, one-dimensional chains, two-dimensional layers and three-dimensional frameworks. The title cyanide-bridged Cu(II)-Co(III) heterometallic compound, [Cu(II)Co(III)(CN)6(C4H11N2)(H2O)]n, has been synthesized and characterized by single-crystal X-ray diffraction analysis, magnetic measurement, thermal study, vibrational spectroscopy (FT-IR) and scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM-EDS). The crystal structure analysis revealed that it has a two-dimensional grid-like structure built up of [Cu(Hpip)(H2O)](3+) cations (Hpip is piperazinium) and [Co(CN)6](3-) anions that are linked through bridging cyanide ligands. The overall three-dimensional supramolecular network is expanded by a combination of interlayer O-H...N and N-H...O hydrogen bonds involving the coordinated water molecules and the N atoms of the nonbridging cyanide groups and monodentate cationic piperazinium ligands. A magnetic investigation shows that antiferromagnetic interactions exist in the title compound.
Keywords: TOPOS analysis; antiferromagnetic coupling; cobalt(III); copper(II); crystal structure; heterometallic; hexacyanidocobaltate; hydrogen bonding; piperazinium; two-dimensional coordination polymer.