Determination of hydrophobicity of dry-heated wheat starch granules using sucrose fatty acid esters (SFAE)

Biosci Biotechnol Biochem. 2014;78(9):1572-6. doi: 10.1080/09168451.2014.923293. Epub 2014 Jun 17.

Abstract

Sucrose fatty acid esters (SFAE) were adsorbed onto dry-heated (120 °C for 10, 20, 40, 60, and 120 min) wheat starch granules and extracted with ethyl ether in a Soxhlet apparatus without gelatinization of the starch granules. The amount of sucrose in the extracted SFAE was determined by the phenol sulfate method. A gradual increase of the sucrose from 159 to 712 μg, in SFAE per gram of starch, occurred with increasing dry-heating time and demonstrated the increased hydrophobicity of the starch granules. Increase of the SFAE was highly correlated (r = 0.9816) to increase of the oil-binding capacity of the dry-heated wheat starch granules. Non-waxy rice, waxy rice, sweet potato, and potato starch granules also showed higher hydrophobicity after dry-heating by this method.

Keywords: SFAE; dry-heated starch granule; hydrophobicity; oil-binding capacity.

MeSH terms

  • Esters / chemistry
  • Fatty Acids / chemistry*
  • Hydrophobic and Hydrophilic Interactions*
  • Starch / chemistry*
  • Sucrose / chemistry
  • Triticum / chemistry*
  • Waxes / chemistry

Substances

  • Esters
  • Fatty Acids
  • Waxes
  • Sucrose
  • Starch