Superionic Conducting Halide Frameworks Enabled by Interface-Bonded Halides.
Fu J, Wang S, Liang J, Alahakoon SH, Wu D, Luo J, Duan H, Zhang S, Zhao F, Li W, Li M, Hao X, Li X, Chen J, Chen N, King G, Chang LY, Li R, Huang Y, Gu M, Sham TK, Mo Y, Sun X.
Fu J, et al.
J Am Chem Soc. 2023 Feb 1;145(4):2183-2194. doi: 10.1021/jacs.2c09446. Epub 2022 Dec 30.
J Am Chem Soc. 2023.
PMID: 36583711
Here, we report a new class of zeolite-like halide frameworks, SmCl(3), for example, in which 1-dimensional channels are enclosed by [SmCl(9)](6-) tricapped trigonal prisms to provide a short jumping distance of 2.08 A between two octahedra for Li(+) ion hopping. ...
Here, we report a new class of zeolite-like halide frameworks, SmCl(3), for example, in which 1-dimensional channels are enclosed by [SmCl(9 …