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Redox-mediated formation of plutonium oxide nanoparticles.
Romanchuk AY , Plakhova TV , Egorov AV , Egorova TB , Dorovatovskii PV , Zubavichus YV , Shiryaev AA , Kalmykov SN . Romanchuk AY , et al. Dalton Trans. 2018 Aug 14;47(32):11239-11244. doi: 10.1039/c8dt02396d. Dalton Trans. 2018. PMID: 30058661
Precipitates formed by the neutralisation of Pu(iii), Pu(iv), Pu(v), and Pu(vi) solutions were characterised by HRTEM, SAXS, and XRD in the suspensions. PuO2 nanoparticles uniform in size (typical diameter around 2.5 nm) and phase composition were observed in all cases und …
Precipitates formed by the neutralisation of Pu(iii), Pu(iv), Pu(v), and Pu(vi) solutions were characterised by HRTEM, SAXS, and XRD …
Towards the surface hydroxyl species in CeO2 nanoparticles.
Plakhova TV , Romanchuk AY , Butorin SM , Konyukhova AD , Egorov AV , Shiryaev AA , Baranchikov AE , Dorovatovskii PV , Huthwelker T , Gerber E , Bauters S , Sozarukova MM , Scheinost AC , Ivanov VK , Kalmykov SN , Kvashnina KO . Plakhova TV , et al. Nanoscale. 2019 Oct 10;11(39):18142-18149. doi: 10.1039/c9nr06032d. Nanoscale. 2019. PMID: 31555787
Synchrotron X-ray absorption experiments at Ce L3 and M5 edges, combined with X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) and small angle X-ray scattering (SAXS) and theoretical calculations demonstrate that in addition to the nanoceri …
Synchrotron X-ray absorption experiments at Ce L3 and M5 edges, combined with X-ray diffraction (XRD), high-resolution transmission electron …