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Quantification of chemicals in non-targeted analysis without analytical standards - Understanding the mechanism of electrospray ionization and making predictions.
Johnson TA, Abrahamsson DP. Johnson TA, et al. Curr Opin Environ Sci Health. 2024 Feb;37:100529. doi: 10.1016/j.coesh.2023.100529. Epub 2023 Dec 19. Curr Opin Environ Sci Health. 2024. PMID: 38312491
The constant creation and release of new chemicals to the environment is forming an ever-widening gap between available analytical standards and known chemicals. ...
The constant creation and release of new chemicals to the environment is forming an ever-widening gap between available analytical st …
Total shoulder prosthesis with humeral resurfacing: Impact on lateral offset and short-term clinical consequences.
Camus D, Galland A, Airaudi S, Mancini J, Gravier R. Camus D, et al. Orthop Traumatol Surg Res. 2018 Oct;104(6):787-791. doi: 10.1016/j.otsr.2018.01.015. Epub 2018 Mar 16. Orthop Traumatol Surg Res. 2018. PMID: 29555560 Free article.
The primary outcome measure was the change in lateral offset between radiographs obtained pre-operatively and 3 months post-operatively. The functional outcome assessed using the Constant score was compared between the groups with a lateral offset change <10mm vs. 10mm. …
The primary outcome measure was the change in lateral offset between radiographs obtained pre-operatively and 3 months post-operatively. The …
Application of multivariate statistics to vestibular testing: discriminating between Menière's disease and migraine associated dizziness.
Dimitri PS, Wall C 3rd, Oas JG, Rauch SD. Dimitri PS, et al. J Vestib Res. 2001;11(1):53-65. J Vestib Res. 2001. PMID: 11673678
Sinusoidal harmonic acceleration test variables were reduced to three vestibulo-ocular reflex physiologic parameters: gain, time constant, and asymmetry. A combination of these parameters plus a measurement of reduced vestibular response from caloric testing allowed us to …
Sinusoidal harmonic acceleration test variables were reduced to three vestibulo-ocular reflex physiologic parameters: gain, time constant
Fundamental signatures of short- and long-range electron transfer for the blue copper protein azurin at Au/SAM junctions.
Khoshtariya DE, Dolidze TD, Shushanyan M, Davis KL, Waldeck DH, van Eldik R. Khoshtariya DE, et al. Proc Natl Acad Sci U S A. 2010 Feb 16;107(7):2757-62. doi: 10.1073/pnas.0910837107. Epub 2010 Feb 1. Proc Natl Acad Sci U S A. 2010. PMID: 20133645 Free PMC article.
Fast scan cyclic voltammetry and a Marcus equation analysis were used to determine unimolecular standard rate constants and reorganization free energies for variable n, temperature (2-55 degrees C), and pressure (5-150 MPa) conditions. A novel global fitting procedure was …
Fast scan cyclic voltammetry and a Marcus equation analysis were used to determine unimolecular standard rate constants and reorganiz …
Fracture of the Duromedics mitral valve housing with leaflet escape.
Dimitri WR, Williams BT. Dimitri WR, et al. J Cardiovasc Surg (Torino). 1990 Jan-Feb;31(1):41-6. J Cardiovasc Surg (Torino). 1990. PMID: 2182642 Review.
Whilst intrinsic structural failure is increasingly uncommon constant clinical awareness of its occurrence in a patient with a mechanical valve presenting with unexplained acute heart failure and pulmonary oedema, and prompt surgical intervention offers the best chance of …
Whilst intrinsic structural failure is increasingly uncommon constant clinical awareness of its occurrence in a patient with a mechan …
Classification of human rotation test results using parametric modeling and multivariate statistics.
Dimitri PS, Wall C 3rd, Oas JG. Dimitri PS, et al. Acta Otolaryngol. 1996 Jul;116(4):497-506. doi: 10.3109/00016489609137880. Acta Otolaryngol. 1996. PMID: 8831833
For each patient, models reduce the large set of SHA test variables to three key parameters: asymptotic gain, vestibulo-ocular reflex time constant, and bias. In addition, the new technique objectively adjusts these parameters for the patient's age. ...
For each patient, models reduce the large set of SHA test variables to three key parameters: asymptotic gain, vestibulo-ocular reflex time …
Kinetic, thermodynamic, and mechanistic patterns for free (unbound) cytochrome c at Au/SAM junctions: impact of electronic coupling, hydrostatic pressure, and stabilizing/denaturing additives.
Khoshtariya DE, Dolidze TD, Seifert S, Sarauli D, Lee G, van Eldik R. Khoshtariya DE, et al. Chemistry. 2006 Sep 18;12(27):7041-56. doi: 10.1002/chem.200600059. Chemistry. 2006. PMID: 16888736
We report for the first time a mechanistic changeover detected for "free" CytC by three independent kinetic methods, manifested through 1) the abrupt change in the dependence of the shape of the electron exchange standard rate constant (k(o)) versus the SAM thickness (resu …
We report for the first time a mechanistic changeover detected for "free" CytC by three independent kinetic methods, manifested through 1) t …
Multiple mechanisms for electron transfer at metal/self-assembled monolayer/room-temperature ionic liquid junctions: dynamical arrest versus frictional control and non-adiabaticity.
Khoshtariya DE, Dolidze TD, van Eldik R. Khoshtariya DE, et al. Chemistry. 2009;15(21):5254-62. doi: 10.1002/chem.200802450. Chemistry. 2009. PMID: 19343756
Electrochemical devices consisting of gold electrodes coated by electronically well-behaved self-assembled alkanethiol monolayers of variable thickness, a ferrocene/ferrocenium redox probe and a typical room-temperature ionic liquid (RTIL) [bmim][NTf(2)] (1-butyl-3-methylimidazol …
Electrochemical devices consisting of gold electrodes coated by electronically well-behaved self-assembled alkanethiol monolayers of variabl …