Laser-Assisted Synthesis of Composite Nanoparticles of Perovskite BaTiO₃ in Aqueous Solutions and Their Optical Properties

Experimental results are presented on laser-assisted synthesis of composite nanoparticles of perovskite BaTiO₃ with gold nanoparticles using the technique of laser ablation in water and aqueous solution of hydrogen peroxide. Nanoparticles of BaTiO₃ are generated by near IR laser radiation with pulse durations of 170 fs, 1 ps, and 200 ns. Nanoparticles of barium titanate BaTiO₃ (BTO) have tetragonal structure for all used pulse durations. Two ways of synthesis are tested. In the first one a gold target is ablated in the colloidal solution of BaTiO₃ nanoparticles. The second way consists of laser exposure of the mixture of colloidal solutions of nanoparticles of BaTiO₃ and Au. Synthesized composite nanoparticles are characterized by optical spectroscopy, Raman spectroscopy, X-Ray diffractometry, and Transmission Electron Microscopy. Composite BaTiO₃‑Au nanoparticles have the absorption band in the visible range of spectrum and demonstrate plasmonic luminescence.