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Showing results for xu qin bu
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Synthesis of iridium and rhodium complexes with new chiral phosphine-NHC ligands based on 1,1'-binaphthyl framework and their application in asymmetric hydrogenation.
Gu P, Zhang J, Xu Q, Shi M. Gu P, et al. Among authors: xu q. Dalton Trans. 2013 Oct 7;42(37):13599-606. doi: 10.1039/c3dt51141c. Epub 2013 Jul 30. Dalton Trans. 2013. PMID: 23900600
After deprotonation of these phosphine-imidazolium salts with LiO(t)Bu, and subsequent complexation with [Ir(COD)Cl]2 and anion exchange with NaBArF, phosphine-carbene chelated iridium complexes (R)-6a and (R)-6b were obtained. ...
After deprotonation of these phosphine-imidazolium salts with LiO(t)Bu, and subsequent complexation with [Ir(COD)Cl]2 and anion excha …