The present work follows our previous study dealing with a new type of synchronization in a system of two weakly coupled generalized van der Pol-Duffing autogenerators. The essence of the effect revealed is that the synchronized oscillations are not stationary but accompanied by the most intensive energy exchange between the oscillators. The phase shift between the generators remains constant most of the time, except for vanishingly small transitional intervals. The current analysis deals with a generalized model in order to clarify the frequency detuning effect. We found that varying the frequency detuning, nonlinearity, and dissipation parameters can lead to structural changes in phase diagrams of the energy exchange dynamics, with important transitions from the intensive energy exchange to its localization on one of the two oscillators. The main conclusion is that stationary and nonstationary synchronizations associate with nonlinear normal and local modes, respectively. The analysis uses phase plane diagrams, including the concept of limiting phase trajectories, whose role in nonstationary synchronization appears to be similar to the role of nonlinear normal modes in conventional stationary states.