Synergetic Strategy for the Fabrication of Self-Standing Distorted Carbon Nanofibers with Heteroatom Doping for Sodium-Ion Batteries

Sayali B Kale; Ujjwala P Chothe; Bharat B Kale; Milind V Kulkarni; Sampath Pavitran; Suresh W Gosavi

doi:10.1021/acsomega.1c00922

Synergetic Strategy for the Fabrication of Self-Standing Distorted Carbon Nanofibers with Heteroatom Doping for Sodium-Ion Batteries

ACS Omega. 2021 Jun 12;6(24):15686-15697. doi: 10.1021/acsomega.1c00922. eCollection 2021 Jun 22.

Authors

Sayali B Kale¹, Ujjwala P Chothe², Bharat B Kale², Milind V Kulkarni², Sampath Pavitran^{1

3}, Suresh W Gosavi^{4

5}

Affiliations

¹ Department of Technology, Savitribai Phule Pune University (Formerly University of Pune), Ganeshkhind Road, Pune 411007, India.
² Centre for Materials for Electronics Technology (C-MET), Ministry of Electronics and Information Technology (MeitY), Panchavati, Off Pashan Road, Pune 411008, India.
³ Department of Mechanical Engineering, Vishwakarma Institute of Technology Pune, Pune 411 037, India.
⁴ Department of Physics, Savitribai Phule Pune University (Formerly University of Pune), Ganeshkhind Road, Pune 411 007, India.
⁵ Photocatalysis International Research Center, Research Institute for Science & Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan.

Abstract

Currently, the limited availability of lithium sources is escalating the cost of lithium-ion batteries (LIBs). Considering the fluctuating economics of LIBs, sodium-ion batteries (SIBs) have now drawn attention because sodium is an earth-abundant, low-cost element that exhibits similar chemistry to that of LIBs. Despite developments in different anode materials, there still remain several challenges in SIBs, including lighter cell design for SIBs. The presented work designs a facile strategy to prepare nitrogen-doped free-standing pseudo-graphitic nanofibers via electrospinning. A structural and morphological study implies highly disordered graphitic structured nanofibers having diameters of ∼120-170 nm, with a smooth surface. X-ray photoelectron spectroscopy analysis showed that nitrogen was successfully doped in carbon nanofibers (CNFs). When served as an anode material for SIBs, the resultant material exhibits excellent sodium-ion storage properties in terms of long-term cycling stability and high rate capability. Notably, a binder-free self-standing CNF without a current collector was used as an anode for SIBs that delivered capacities of 210 and 87 mA h g^-1 at 20 and 1600 mA g^-1, respectively, retaining a capacity of 177 mA h g^-1 when retained at 20 mA g^-1. The as-synthesized CNFs demonstrate a long cycle life with a relatively high Columbic efficiency of 98.6% for the 900th cycle, with a stable and excellent rate capacity. The sodium storage mechanisms of the CNFs were examined with various nitrogen concentrations and carbonization temperatures. Furthermore, the diffusion coefficients of the sodium ions based on the electrochemical impedance spectra measurement have been calculated in the range of 10^-15-10^-12 cm² s^-1, revealing excellent diffusion mobility for Na atoms in the CNFs. This study demonstrates that optimum nitrogen doping and carbonization temperature demonstrated a lower Warburg coefficient and a higher Na-ion diffusion coefficient leads to enhanced stable electrochemical performance. Thus, our study shows that the nitrogen-doped CNFs will have potential for SIBs.