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Page 1
Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile.
Kamer J, Schleier D, Donker M, Hemberger P, Bodi A, Bouwman J. Kamer J, et al. Phys Chem Chem Phys. 2023 Nov 1;25(42):29070-29079. doi: 10.1039/d3cp03977c. Phys Chem Chem Phys. 2023. PMID: 37861750
The seven lowest energy dissociative photoionization channels of benzonitrile were found to yield CN + c-C(6)H(5)(+), HCN + C(6)H(4)(+), C(2)H(4) + HC(5)N(+), HC(3)N + C(4)H(4)(+), H(2)C(3)N + C(4)H(3)(+), CH(2)CHCN + C(4)H( …
The seven lowest energy dissociative photoionization channels of benzonitrile were found to yield CN + c-C(6)H(5)(+), HCN + …
Impact of opioid-free analgesia on pain severity and patient satisfaction after discharge from surgery: multispecialty, prospective cohort study in 25 countries.
TASMAN Collaborative. TASMAN Collaborative. Br J Surg. 2024 Jan 3;111(1):znad421. doi: 10.1093/bjs/znad421. Br J Surg. 2024. PMID: 38207169 Free PMC article.

After adjustment for confounders, opioid analgesia on discharge was independently associated with increased pain severity (risk ratio 1.52, 95% c.i. 1.31 to 1.76; P < 0.001) and re-presentation to healthcare providers owing to side-effects of medication (OR 2.38, 95%

…
After adjustment for confounders, opioid analgesia on discharge was independently associated with increased pain severity (risk ratio 1.52, …
A radiation belt of energetic protons located between Saturn and its rings.
Roussos E, Kollmann P, Krupp N, Kotova A, Regoli L, Paranicas C, Mitchell DG, Krimigis SM, Hamilton D, Brandt P, Carbary J, Christon S, Dialynas K, Dandouras I, Hill ME, Ip WH, Jones GH, Livi S, Mauk BH, Palmaerts B, Roelof EC, Rymer A, Sergis N, Smith HT. Roussos E, et al. Science. 2018 Oct 5;362(6410):eaat1962. doi: 10.1126/science.aat1962. Science. 2018. PMID: 30287631
The Cassini spacecraft's Magnetosphere Imaging Instrument obtained measurements of a radiation belt that lies just above Saturn's dense atmosphere and is decoupled from the rest of the magnetosphere by the planet's A- to C-rings. ...Strong proton depletions that map …
The Cassini spacecraft's Magnetosphere Imaging Instrument obtained measurements of a radiation belt that lies just above Saturn's den …
Exploring the Chemical Dynamics of Phenylethynyl Radical (C(6)H(5)CC; X(2)A(1)) Reactions with Allene (H(2)CCCH(2); X(1)A(1)) and Methylacetylene (CH(3)CCH; X(1)A(1)).
Goettl SJ, Yang Z, Kollotzek S, Paul D, Kaiser RI, Somani A, Portela-Gonzalez A, Sander W, Nikolayev AA, Azyazov VN, Mebel AM. Goettl SJ, et al. J Phys Chem A. 2023 Jul 13;127(27):5723-5733. doi: 10.1021/acs.jpca.3c03077. Epub 2023 Jul 4. J Phys Chem A. 2023. PMID: 37401904 Free PMC article.
These intermediates underwent unimolecular decomposition via atomic hydrogen loss through tight exit transition states in facile radical additionhydrogen atom elimination mechanisms forming predominantly 3,4-pentadien-1-yn-1-ylbenzene (C(6)H(5)CCCHCCH(2)) and 1-phenyl-1,3- …
These intermediates underwent unimolecular decomposition via atomic hydrogen loss through tight exit transition states in facile radical add …
Tailoring of TiAl6V4 Surface Nanostructure for Enhanced In Vitro Osteoblast Response via Gas/Solid (Non-Line-of-Sight) Oxidation/Reduction Reactions.
Ogura N, Berger MB, Srivas P, Hwang S, Li J, Cohen DJ, Schwartz Z, Boyan BD, Sandhage KH. Ogura N, et al. Biomimetics (Basel). 2022 Aug 25;7(3):117. doi: 10.3390/biomimetics7030117. Biomimetics (Basel). 2022. PMID: 36134921 Free PMC article.
An ultrathin (90 16 nm) conformal, titania-based surface layer was first formed by thermal oxidation (600 C, 6 h, air). A calciothermic reduction (CaR) reaction (700 C, 1 h) was then used to convert the surface titania (TiO(2)) into thin layers of calcia (CaO, 77 16 …
An ultrathin (90 16 nm) conformal, titania-based surface layer was first formed by thermal oxidation (600 C, 6 h, air). A calciotherm …
Isotope-specific reactions of acetonitrile (CH3CN) with trapped, translationally cold CCl.
Krohn OA, Catani KJ, Greenberg J, Sundar SP, da Silva G, Lewandowski HJ. Krohn OA, et al. J Chem Phys. 2021 Feb 21;154(7):074305. doi: 10.1063/5.0038113. J Chem Phys. 2021. PMID: 33607907
The gas-phase reaction of CCl(+) with acetonitrile (CH(3)CN) is studied using a linear Paul ion trap coupled to a time-of-flight mass spectrometer. This work builds on a previous study of the reaction of CCl(+) with acetylene [K. ...Nitriles, in particular, are noted for t …
The gas-phase reaction of CCl(+) with acetonitrile (CH(3)CN) is studied using a linear Paul ion trap coupled to a time-of-flight mass …
Protein structure determination by electron diffraction using a single three-dimensional nanocrystal.
Clabbers MTB, van Genderen E, Wan W, Wiegers EL, Gruene T, Abrahams JP. Clabbers MTB, et al. Acta Crystallogr D Struct Biol. 2017 Sep 1;73(Pt 9):738-748. doi: 10.1107/S2059798317010348. Epub 2017 Aug 15. Acta Crystallogr D Struct Biol. 2017. PMID: 28876237 Free PMC article.
Diffraction data were acquired using the rotation method with parallel beam diffraction on a Titan Krios transmission electron microscope equipped with a novel in-house-designed 1024 1024 pixel Timepix hybrid pixel detector for low-dose diffraction data collection. ...
Diffraction data were acquired using the rotation method with parallel beam diffraction on a Titan Krios transmission electron micros …