First-Row Late Transition Metals for Catalytic Alkene Hydrofunctionalisation: Recent Advances in C-N, C-O and C-P Bond Formation

Sophie Bezzenine-Lafollée; Richard Gil; Damien Prim; Jérôme Hannedouche

doi:10.3390/molecules22111901

First-Row Late Transition Metals for Catalytic Alkene Hydrofunctionalisation: Recent Advances in C-N, C-O and C-P Bond Formation

Molecules. 2017 Nov 4;22(11):1901. doi: 10.3390/molecules22111901.

Authors

Sophie Bezzenine-Lafollée¹, Richard Gil², Damien Prim³, Jérôme Hannedouche^{4

5}

Affiliations

¹ Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), UMR 8182, University of Paris-Sud, F-91405 Orsay, France. sophie.bezzenine@u-psud.fr.
² Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), UMR 8182, University of Paris-Sud, F-91405 Orsay, France. richard.gil@u-psud.fr.
³ Institut Lavoisier de Versailles (ILV), UMR 8180, Université Versailles Saint-Quentin, F-78035 Versailles, France. damien.prim@uvsq.fr.
⁴ Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), UMR 8182, University of Paris-Sud, F-91405 Orsay, France. jerome.hannedouche@u-psud.fr.
⁵ Centre National de la Recherche Scientifique (CNRS), UMR8000, Laboratoire de Chimie Physique, F-91405 Orsay, France. jerome.hannedouche@u-psud.fr.

Abstract

This review provides an outline of the most noteworthy achievements in the area of C-N, C-O and C-P bond formation by hydroamination, hydroalkoxylation, hydrophosphination, hydrophosphonylation or hydrophosphinylation reaction on unactivated alkenes (including 1,2- and 1,3-dienes) promoted by first-row late transition metal catalytic systems based on manganese, iron, cobalt, nickel, copper and zinc. The relevant literature from 2009 until mid-2017 has been covered.

Keywords: alcohols; amines; first-row late transition metals; hydrofunctionalisation; phosphorus compounds; unactivated alkenes.

Publication types

Review

MeSH terms

Alkenes / chemistry*
Catalysis
Metals / chemistry*

Substances

Alkenes
Metals