Comparative structural analysis of 5,6,7,9-tetra-O-acetyl-4,8-anhydro-1,3-dideoxy-D-glycero-L-gluco-nonulose and its 1-O-acetylated analog, 1,2,3,4,6-penta-O-acetyl-beta-D-galactopyranose using X-ray crystallography

Rishi Kumar; Pallavi Tiwari; Prakas R Maulik; Anup Kumar Misra

doi:10.1016/j.carres.2005.07.009

Comparative structural analysis of 5,6,7,9-tetra-O-acetyl-4,8-anhydro-1,3-dideoxy-D-glycero-L-gluco-nonulose and its 1-O-acetylated analog, 1,2,3,4,6-penta-O-acetyl-beta-D-galactopyranose using X-ray crystallography

Carbohydr Res. 2005 Oct 17;340(14):2335-9. doi: 10.1016/j.carres.2005.07.009.

Authors

Rishi Kumar¹, Pallavi Tiwari, Prakas R Maulik, Anup Kumar Misra

Affiliation

¹ Medicinal and Process Chemistry Division and Molecular and Structural Biology Division, Central Drug Research Institute, Chattar Manzil Palace, Lucknow 226001, UP, India.

PMID: 16084935
DOI: 10.1016/j.carres.2005.07.009

Abstract

Comparative X-ray diffraction analysis of 5,6,7,9-tetra-O-acetyl-4,8-anhydro-1,3-dideoxy-D-glycero-L-gluco-nonulose (1) and a structurally related analog, 1,2,3,4,6-penta-O-acetyl-beta-D-galactopyranose (2), are reported. Both crystals have one molecule in the unit cell and the pyranose rings in both exist in the 4C1 conformation.

Publication types

Comparative Study
Research Support, Non-U.S. Gov't

MeSH terms

Crystallization
Crystallography, X-Ray / methods
Galactosides / chemistry*
Hot Temperature
Monosaccharides / chemistry*

Substances

Galactosides
Monosaccharides
1,2,3,4,6-penta-O-acetylgalactopyranose