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Bioactive lipids ALIAmides differentially modulate inflammatory responses of distinct subsets of primary human T lymphocytes.
Chiurchiù V, Leuti A, Smoum R, Mechoulam R, Maccarrone M. Chiurchiù V, et al. FASEB J. 2018 Oct;32(10):5716-5723. doi: 10.1096/fj.201800107R. Epub 2018 Jun 7. FASEB J. 2018. PMID: 29879374
Our findings show for the first time that specific ALIAmides can directly affect different T-cell subsets, and provide proof of their anti-inflammatory role in chronic inflammation, ultimately suggesting that these bioactive lipids could offer novel tools for the management of T- …
Our findings show for the first time that specific ALIAmides can directly affect different T-cell subsets, and provide proof of their anti-i …
Mo(CO)6-mediated intramolecular Pauson-Khand reaction of substituted diethyl 3-allyloxy-1-propynylphosphonates.
Moradov D, Al Quntar AA, Youssef M, Smoum R, Rubinstein A, Srebnik M. Moradov D, et al. J Org Chem. 2009 Feb 6;74(3):1029-33. doi: 10.1021/jo801988k. J Org Chem. 2009. PMID: 19108631
Cyclisation of diethyl 3-allyloxy-1-propynylphosphonates with Mo(CO)(6) under PK conditions to give 3-substituted-5-oxo-3,5,6,6a-tetrahydro-1H-cyclopenta[c]furan-4-ylphosphonate, 2a-h, in 45-88% isolated yields was done. The R groups are always syn with H(b) (where applica …
Cyclisation of diethyl 3-allyloxy-1-propynylphosphonates with Mo(CO)(6) under PK conditions to give 3-substituted-5-oxo-3,5,6,6a-tetrahydro- …