Complete Permittivity Tensor in Sputtered CuFe₂O₄ Thin Films at Photon Energies between 2 and 5 eV

Materials (Basel). 2013 Sep 16;6(9):4096-4108. doi: 10.3390/ma6094096.

Abstract

This work is devoted to the systematic study of the optical and magneto-optical properties of sputter deposited CuFe₂O₄ thin films in the photon energy region between 2 and 5 eV using spectroscopic ellipsometry and magneto-optical Kerr spectroscopy. The spectral dependence of both the diagonal and off-diagonal elements of the permittivity tensor is determined. A complete picture about the electron transitions in CuFe₂O₄ is suggested in the frame of intervalence charge transfer and intersublattice charge transfer transitions. The effect of deposition conditions and post-deposition treatment in CuFe₂O₄ films upon the optical and magneto-optical properties is discussed.

Keywords: CuFe2O4; magneto-optics; permittivity tensor; spectroscopic ellipsometry; spinel ferrite.