Algae extract delamination of molybdenum disulfide and surface modification with glycidyl methacrylate and polyaniline for the elimination of metal ions from wastewater

A special type of two-dimensional (2D) material based conducting polymer was constructed by green synthesis and in-situ polymerization techniques. The 2D Molybdenum Disulfide (MoS₂) were first synthesized with the combination of, ammonium tetrathiomolybdate dissolved in 20 mL algae extract under stirring. After stirring for about 2 h, and then finally sulfurization was initiated using sulfur powder in 20 mL of sulfuric solution and stirred for 8 h. The resulting black precipitates of MoS₂ were collected by centrifugation at 5000 rpm. Moreover, the prepared MoS₂ was functionalized with glycidyl methacrylate (GMA) and form the MoS₂@PGMA. Further, the MoS₂@PGMA is combined with polyaniline (PANI) to form conducting polymer grafted thin film nanosheets named MoS₂@PGMA/PANI with a thickness in micrometer size through grafting method. The prepared materials were characterized by SEM, FTIR, XRD, XPS and EDX techniques. To check the performance of materials the adsorption study was performed. Moreover, the adsorption study toward Cu²⁺ and Cd²⁺ showed a tremendous results and the maximum adsorption was 307.7 mg/g and 214.7 mg/g respectively. In addition, the pseudo-first and second order models as well as the adsorption isotherm were investigated using the Langmuir and Freundlich model. The results were best fitted with the pseudo-second order and Langmuir models. The regeneration study was also conducted and MoS₂@PGMA/PANI nanosheets can be easily recycled and restored after five successful recycling. The established methodology for preparing the 2D materials and conducting polymer based MoS₂@PGMA/PANI nanosheets is expected to be applicable for other multiple applications.