Ferrocene containing redox-responsive poly(2-oxazoline)s

Chem Commun (Camb). 2021 Feb 7;57(11):1308-1311. doi: 10.1039/d0cc07830a. Epub 2021 Jan 18.

Abstract

A new monomer, 2-ferrocene-ethyl-2-oxazoline, was copolymerized with 2-alkyl-2-oxazolines. The cationic ring opening polymerization (CROP) of 2-oxazolines allows the synthesis of well-defined copolymers with adjustable molar masses as well as end-group control, which was also evident from kinetic studies. The utilization of this new comonomer led to redox-active polymers as proven by UV-VIS-measurements and cyclic-voltammetry.