First Results on Zinc Oxide Thick Film Deposition by Inverted Magnetron Sputtering for Cyclotron Solid Targets Production

Materials (Basel). 2023 May 18;16(10):3810. doi: 10.3390/ma16103810.

Abstract

The magnetron sputtering technique has been investigated in recent years with ever-growing interest as a verifiable solid target manufacturing technology aimed at the production of medical radionuclides by using low-energy cyclotron accelerators. However, the possible loss of high-cost materials prevents access to work with isotopically enriched metals. The need for expensive materials for the supply of the growing demand for theranostic radionuclides makes the material-saving approach and recovery essential for the radiopharmaceutical field. To overcome the main magnetron sputtering drawback, an alternative configuration is proposed. In this work, an inverted magnetron prototype for the deposition of tens of μm film onto different substrates is developed. Such configuration for solid target manufacturing has been proposed for the first time. Two ZnO depositions (20-30 μm) onto Nb backing were carried out and analysed by SEM (Scanning Electron Microscopy) and XRD (X-ray Diffractogram). Their thermomechanical stability under the proton beam of a medical cyclotron was tested as well. A possible improvement of the prototype and the perspective of its utilisation were discussed.

Keywords: ZnO; cyclotron solid targets; magnetron sputtering; material losses; radioisotope production; ultra-thick deposition.

Grants and funding

This research was funded by the Ministry of Economic Development (MISE), Italy, for 2021–2022, in the framework of the INTEFF_TOTEM project (proof of concept project “Innovazione Tecnologica dalla Fisica Fondamentale_magneTron sputtering cyclOtron TargEt Manufacturing”) promoted by the National Committee of Technological Transfer of INFN. PI: Sara Cisternino.