Modified Jordanian zeolitic tuff in hydrocarbon removal from surface water

This work aims to investigate the potential of Jordanian raw zeolitic tuff (RZT) as oil adsorbent for oil-contaminated water. As hydrophobic properties are the primary determinants of effective oil adsorbents, the hydrophobicity of RZT was enhanced by dealumination process; since the degree of hydrophobicity of zeolites is directly dependent on their aluminum content. The microemulsion modification of the dealuminated zeolitic tuff (TZT) was also applied to increase its hydrophobicity. The raw and modified tuffs were characterized in terms of the surface area and porosity (BET), mineral composition (XRD), microstructure and morphology using scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). In this work, a mixture of water and kerosene was used to examine the hydrophobic/organophilic character of raw and modified zeolitic tuff. Water/dodecane and water/octane mixtures were used to study the kinetics of the adsorption over zeolitic tuff. The results revealed that the sorption capacity using kerosene as a mixed model (water-oil) was enhanced by three- and four-fold for TZT and micro-emulsified zeolitic (MeTZT) tuff respectively. The adsorption capacity of modified zeolitic was compared with that of activated carbon adsorbents.