Improvement of mahogany leaf extract dye fixation on cotton-modal blend

Heliyon. 2023 Oct 7;9(10):e20786. doi: 10.1016/j.heliyon.2023.e20786. eCollection 2023 Oct.

Abstract

The manufacture of regenerated cellulose-based fibers for better mechanical and comfort qualities was stimulated by the rising demand for cotton and the low production rate needed to meet global demands. Modal-cotton blend provides better tensile and moisture management properties. The present work has been designed to sketch out the scope of increased dye fixation or dye uptake opportunity onto the blends. Cotton-modal blend was dyed with mahogany leaf extract dyes avoiding mordant. The higher wash fastness rating 4/5, 5 along with the FTIR characteristic bands around 1190-1210 cm-1 created attention for the confirmation of dye-fibre bonding. But as modal is a regenerated cellulosic fibre, there was a suspect of uneven fixation because of dual way dye penetration options inside the fibre: direct bonding with cotton cellulose and dye penetration into swollen modal fibre through segmental mobility theory. Fortunately the uniformity of shade was affirmed by the determination of evenness through random CMC DE and K/S values at distinguished parts of the same sample. Mordantless mahogany dye fixation on cotton-modal blend was found even at the elevated dyeing temperature of 130 °C. The detailed CIE Lab data explored the close symmetry and uniformity of the dyeing outcomes of the blend.

Keywords: Color fastness; Eco-friendly; Mahogany leaf; Mordantless; Natural dye.