New ZnO-Based Glass Ceramic Sensor for H₂ and NO₂ Detection

Sensors (Basel). 2017 Nov 3;17(11):2538. doi: 10.3390/s17112538.

Abstract

In this study, a glass ceramic with a nominal composition 58ZnO:4Bi₂O₃:4WO₃:33.3B₂O₃ was synthesized by melt quenching technique. A gas sensor was then manufactured using a ZnO sol-gel phase as a permanent binder of the glass-ceramic to an alumina substrate having interdigitated electrodes. The film sensitivity towards humidity, NH₃, H₂ and NO₂ was studied at different temperatures. X-ray diffraction technique (XRD), field emission- scanning electron microscopy (FE-SEM) and differential thermal analysis (DTA) were used to characterize the prepared material. Though the response in the sub-ppm NO₂ concentration range was not explored, the observed results are comparable with the latest found in the literature.

Keywords: NO2 monitoring; ZnO; electrical properties; glass ceramics; sensors.