The response of Vertisols to contamination by heavy metals (As, Cd, Pb, Hg) and micronutrients (Co, Cu, Cr, Ni, V, Zn) in toxic concentrations was studied in a series of experiments undertaken with soil samples from the province of Malaga, in Southern Spain. The soil samples were placed in methacrylate columns, passing through a contaminant solution of selected elements in order to study their distribution and fixation the soil. Systematic sampling and sequential extraction analysis show that the Vertisols behave as a buffer to all elements, except cadmium.