Grafting the Charged Functional Groups on Carbon Nanotubes for Improving the Efficiency and Stability of Capacitive Deionization Process

In the capacitive deionization (CDI) process, the degradation of desalting performance is predominantly due to the co-ion expulsion effect and electrode oxidation. To overcome these complications, carbon nanotubes grafted with amine and sulfonic functional groups respectively were prepared and used as the CDI electrodes. The structural characterizations and performance tests confirmed that a uniform functional layer was formed on the surface of the modified electrodes and it enhanced the ion selectivity and wettability of the electrode surface. Moreover, the effects of the functional layer on the electrode stability were investigated by circulating CV tests and desalination tests. The positive shift value of the potential of zero charge (PZC) for the as-prepared electrodes was tested as a quantitative indication for their possible surface oxidation during cyclic tests. Analysis of the PZC variation and desalting performance demonstrated that the excellent desalting stability was achieved by the Cell N-S assembled with the ammoniated CNTs electrode as anode and sulfonated CNTs electrode as cathode. Because the functional layer could preserve the pores system on the modified electrodes and diminish the parasitic reactions that exacerbate the electrode oxidation. This work provides an effective strategy for promoting the electrode performance and prolonging the life of the electrode.