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Page 1
An Epoxide Intermediate in Glycosidase Catalysis.
Sobala LF, Speciale G, Zhu S, Raich L, Sannikova N, Thompson AJ, Hakki Z, Lu D, Shamsi Kazem Abadi S, Lewis AR, Rojas-Cervellera V, Bernardo-Seisdedos G, Zhang Y, Millet O, Jiménez-Barbero J, Bennet AJ, Sollogoub M, Rovira C, Davies GJ, Williams SJ. Sobala LF, et al. ACS Cent Sci. 2020 May 27;6(5):760-770. doi: 10.1021/acscentsci.0c00111. Epub 2020 Apr 16. ACS Cent Sci. 2020. PMID: 32490192 Free PMC article.
Quantum mechanics/molecular mechanics modeling of the reaction coordinate predicted a reaction pathway through a 1,2-anhydro sugar via a transition state in an unusual flattened, envelope (E (3)) conformation. Kinetic isotope effects (k (cat)/K (M)) for anomeric-(2)H and a …
Quantum mechanics/molecular mechanics modeling of the reaction coordinate predicted a reaction pathway through a 1,2-anhydro sugar via a tra …
Secondary-Rim γ-Cyclodextrin Functionalization to Conjugate with C60 : Improved Efficacy as a Photosensitizer.
Zhu X, Quaranta A, Bensasson RV, Sollogoub M, Zhang Y. Zhu X, et al. Chemistry. 2017 Jul 18;23(40):9462-9466. doi: 10.1002/chem.201700782. Epub 2017 Jun 29. Chemistry. 2017. PMID: 28548683
DIBAL-H-mediated demethylation provides a novel method to access secondary-rim functionalized gamma-cyclodextrin. 2(A) ,3(B) -Dihydroxyl-per-O-methylated-gamma-cyclodextrin has been obtained, whose conjugation with C(60) allows access to the most water-soluble C(60) conjugate des …
DIBAL-H-mediated demethylation provides a novel method to access secondary-rim functionalized gamma-cyclodextrin. 2(A) ,3(B) -Dihydroxyl-per …
Beta cyclodextrins bind, stabilize, and remove lipofuscin bisretinoids from retinal pigment epithelium.
Nociari MM, Lehmann GL, Perez Bay AE, Radu RA, Jiang Z, Goicochea S, Schreiner R, Warren JD, Shan J, Adam de Beaumais S, Ménand M, Sollogoub M, Maxfield FR, Rodriguez-Boulan E. Nociari MM, et al. Proc Natl Acad Sci U S A. 2014 Apr 8;111(14):E1402-8. doi: 10.1073/pnas.1400530111. Epub 2014 Mar 24. Proc Natl Acad Sci U S A. 2014. PMID: 24706818 Free PMC article.
Mapping C-H⋅⋅⋅M Interactions in Confined Spaces: (α-ICyDMe )Au, Ag, Cu Complexes Reveal "Contra-electrostatic H Bonds" Masquerading as Anagostic Interactions*.
Dos Passos Gomes G, Xu G, Zhu X, Chamoreau LM, Zhang Y, Bistri-Aslanoff O, Roland S, Alabugin IV, Sollogoub M. Dos Passos Gomes G, et al. Chemistry. 2021 Jun 1;27(31):8127-8142. doi: 10.1002/chem.202100263. Epub 2021 May 6. Chemistry. 2021. PMID: 33769617 Free article.
While electrostatics is strongly stabilizing component in the conventional C-HX bonds where X is an electronegative main group element, it is destabilizing in the C-HM contacts when M is Au(I), Ag(I), or Cu(I) of NHC-M-Cl systems. Such remarkable C-HM interaction be …
While electrostatics is strongly stabilizing component in the conventional C-HX bonds where X is an electronegative main group element, it i …
Stable DNA triple helix formation using oligonucleotides containing 2'-aminoethoxy,5-propargylamino-U.
Sollogoub M, Darby RA, Cuenoud B, Brown T, Fox KR. Sollogoub M, et al. Biochemistry. 2002 Jun 11;41(23):7224-31. doi: 10.1021/bi020164n. Biochemistry. 2002. PMID: 12044153
UV- and fluorescence melting studies with intramolecular triplexes confirmed that the bis-modified base produces a much greater increase in T(m) than either modification alone....
UV- and fluorescence melting studies with intramolecular triplexes confirmed that the bis-modified base produces a much greater increase in …
Biodegradable PLA/PBSA Multinanolayer Nanocomposites: Effect of Nanoclays Incorporation in Multinanolayered Structure on Mechanical and Water Barrier Properties.
Messin T, Follain N, Lozay Q, Guinault A, Delpouve N, Soulestin J, Sollogoub C, Marais S. Messin T, et al. Nanomaterials (Basel). 2020 Dec 20;10(12):2561. doi: 10.3390/nano10122561. Nanomaterials (Basel). 2020. PMID: 33419300 Free PMC article.
The cloisite 30B (C30B) filler incorporation in nanolayers was considered to be an improvement of barrier properties of the multilayer films additional to the confinement effect resulting to forced assembly during the multilayer coextrusion process. 2049-layer films of ~300 m
The cloisite 30B (C30B) filler incorporation in nanolayers was considered to be an improvement of barrier properties of the multilayer films …
Orchestrating Communications in a Three-Type Chirality Totem: Remote Control of the Chiroptical Response of a Möbius Aromatic System.
Benchouaia R, Cissé N, Boitrel B, Sollogoub M, Le Gac S, Ménand M. Benchouaia R, et al. J Am Chem Soc. 2019 Jul 24;141(29):11583-11593. doi: 10.1021/jacs.9b04074. Epub 2019 Jul 9. J Am Chem Soc. 2019. PMID: 31251054 Free article.
Over the past decade, [28]hexaphyrins have been revealed to be among the best candidates to build on Mobius aromaticity. Whereas their flexibility needs to be controlled to get P/M twist enantioselectivity, it could be of great interest to sustain dynamic chirality transfe …
Over the past decade, [28]hexaphyrins have been revealed to be among the best candidates to build on Mobius aromaticity. Whereas their flexi …