Face-Fusion of Icosahedral Boron Hydride Increases Affinity to γ-Cyclodextrin: closo,closo-[B21 H18 ]- as an Anion with Very Low Free Energy of Dehydration.
Assaf KI, Holub J, Bernhardt E, Oliva-Enrich JM, Fernández Pérez MI, Canle M, Santaballa JA, Fanfrlík J, Hnyk D, Nau WM.
Assaf KI, et al.
Chemphyschem. 2020 May 18;21(10):971-976. doi: 10.1002/cphc.201901225. Epub 2020 Apr 7.
Chemphyschem. 2020.
PMID: 32163219
Free PMC article.
The thermodynamic signature of solution-phase binding is exceptional, the association constant for the gamma-CD complex with B(21) H(18)(-) reaches 1.810(6) M(-1) , which is on the same order of magnitude as the so far highest observed value for the complex between gamma-C …
The thermodynamic signature of solution-phase binding is exceptional, the association constant for the gamma-CD complex with B(21) H(18)(-) …