Influence of monoammonium phosphate on glyphosate adsorption-desorption in tropical soils: Effect of the order of sorbate additions

Glyphosate and phosphate compete for the same adsorption sites in the soil because their adsorption mechanisms are similar as the herbicide contains a phosphate group. However, how this competition occurs in relation to the order of addition of the sorbate and the composition of the soils remains unclear. The effect of the soil clay composition and the order of glyphosate and monoammonium phosphate (MAP) additions on glyphosate sorption-desorption was investigated using three inceptisols collected from Colombian rice fields. Glyphosate adsorption isotherms were evaluated using the batch equilibrium method and were modeled applying the Freundlich equation. The values for glyphosate K_fa, when evaluated alone, ranged from 14.39 to 639.86 mg^1-na L^na kg^-1. An agreement was found between adsorbed glyphosate, chlorites, and low initial phosphorous soil content. Preadsorbed MAP or simultaneous MAP-glyphosate additions to the soil revealed a drastic reduction in glyphosate K_fa values in soil containing the highest amount of 2 × 1 clays, but kaolinitic soils remained practically unaffected. Low desorption values could be associated with soils with the highest kaolinite content. Glyphosate remobilization was favored when the desorbing MAP solution was used in soils containing preadsorbed glyphosate. This study provides new knowledge on the effect of phosphorus fertilizers on glyphosate bioavailability in soils with different mineral compositions.