Three polyimides and six inorganic fillers in a form of nanometer-sized particles were studied as thick film solution cast mixed matrix membranes (MMMs) for the transport of CO₂, CH₄, and H₂O. Gas transport properties and electron microscopy images indicate good polymer-filler compatibility for all membranes. The only filler type thatdemonstrated good distribution throughout the membrane thickness at 10 wt. % loading was BaCe0.2Zr0.7Y0.1O₃ (BCZY). The influence of this filler on MMM gas transport properties was studied in detail for 6FDA-6FpDA in a filler content range from one to 20 wt. % and for Matrimid® and P84® at 10 wt. % loading. The most promising result was obtained for Matrimid®-10wt. % BCZY MMM, which showed improvement in CO₂ and H₂O permeabilities accompanied by increased CO₂/CH₄ selectivity and high water selective membrane at elevated temperatures without H₂O/permanent gas selectivity loss.
Keywords: carbon dioxide; gas separation membranes; inorganic fillers; mixed matrix membranes; polyimides; water transport; water vapor permeability.