Recently, fire and explosion accidents associated with lithium ion battery failure occurred frequently. Safety has become one of the main constraints on the wide application of lithium ion batteries in the field of electric vehicles (EVs). By using a simultaneous thermal analyzer (STA8000) and accelerating rate calorimetry (ARC), we studied the thermal stability of high nickel battery materials and the high temperature thermal runaway of the battery, combining the two experimental results to analyze the battery thermal runaway process. We studied the temperature difference between inside and outside during thermal runaway by arranging two temperature sensors inside and outside the battery. The chemical reactions of the battery at high temperature through the thermal performance of the anode, cathode, and separator are also revealed. In-depth exploration of the occurrence process and the trigger mechanism of thermal runaway of lithium batteries was made. The main findings of the study are as follows: The temperature at which the anode materials begin to decompose is 77.13 °C, caused by decomposition of the solid electrolyte interface and the temperature at which the cathode materials begin to decompose is 227.09 °C. The maximum surface temperature of the battery during thermal runaway is 641.41 °C; and the maximum inside temperature of the battery is 1117.80 °C. The time difference between the maximum temperatures inside and outside the battery is 40 s. The thermal runaway temperature of the battery T c is 228.47 °C, which is mainly contributed by the internal short circuit of the anode and cathode to release Joule heat and the cathode/electrolyte reaction. The maximum temperature of T m is 642.65 °C, which is mainly caused by the reaction between oxygen and electrolyte.
© 2022 The Authors. Published by American Chemical Society.